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Spectra and structure for Bi0-BiCl3-Li, K/Cl

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Theoretical and Experimental Chemistry Aims and scope

Abstract

Raman-scattering, electronic-absorption, and ESR spectra have been used to determine the states of bismuth and the structures of the compounds formed in molten chloride systems; it is found that BiCl4 − with Td symmetry are formed in BiCl3-Li, K/Cleu melts, while a Bi0-BiCl3-Li, K/Cleu melt produces the BiCl4 − ⇄ BiCl3 + Cl−; BiCl3 + Bi0 ⇄ Bi2Cl3 equilibria with the formation of Cl− the quasitetrahedral

ion in the second stage, which has a metal-bond and a single unpaired electron.

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Authors
  1. C. V. Volkov
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  2. N. I. Buryak
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  3. V. F. Kozin
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  4. I. A. Sheka
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Additional information

Institute for General and Inorganic Chemistry, Academy of Sciences of the Ukrainian SSR, Kiev. Translated from Teoreticheskaya i Éksperimental'naya Khimiya, Vol. 27, No. 3, pp. 311–315, May–June, 1991. Original article submitted September 12, 1988.

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Volkov, C.V., Buryak, N.I., Kozin, V.F. et al. Spectra and structure for Bi0-BiCl3-Li, K/Cl. Theor Exp Chem 27, 270–273 (1991). https://doi.org/10.1007/BF01372492

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  • DOI: https://doi.org/10.1007/BF01372492

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