Abstract
We present the results of a calorimetric investigation of the enthalpies of mixing in Ge-Zr and Ge-Nb systems at 1973 K in the range 0 to 22 at.%. We show that alloy formation in these systems is accompanied by a large exothermic effect. This is connected with the large influence of binary intermetallic compounds in the Ge-Zr and Ge-Nb systems.
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Taras Shevchenko National University. Translated from Poroshkovaya Metallurgiya, Nos. 7–8, pp. 76–79, July–August, 1996.
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Beloborodova, E.A. Thermodynamic properties of liquid alloys of germanium with d-transition metals. Powder Metall Met Ceram 35, 389–391 (1996). https://doi.org/10.1007/BF01329229
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DOI: https://doi.org/10.1007/BF01329229