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Evidence forsp 3-carbons in Rb1C60 from13C MAS NMR

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Zeitschrift für Physik B Condensed Matter

Abstract

We report on13C MAS NMR experiments in the low temperature phase of Rb1C60. Two different lines are observed with line shifts of ≈110 ppm and ≈50 ppm. The line at 50 ppm is a signature ofsp 3 carbons and can be interpreted in terms of a hypothetical “polymerization” along the crystallographica-axis. This supports a quasi 1 D structure of the A1C60 in the low temperature phase.

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  1. 2. Physikalisches Institut, Universität Stuttgart, Pfaffenwaldring 57, D-70550, Stuttgart, Germany

    T. Kälber, G. Zimmer & M. Mehring

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  1. T. Kälber
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  2. G. Zimmer
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  3. M. Mehring
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Kälber, T., Zimmer, G. & Mehring, M. Evidence forsp 3-carbons in Rb1C60 from13C MAS NMR. Z. Physik B - Condensed Matter 97, 1–2 (1995). https://doi.org/10.1007/BF01317580

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  • DOI: https://doi.org/10.1007/BF01317580

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