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Indirect spectrophotometric determination of cyanide

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Abstract

A spectrophotometric method for cyanide based on its inhibition of the colour formation reaction between nickel(II) and 3-(4′,5′-dimethyl-2′-thiazolylazo)-2,6-dihydroxybenzoic acid has been developed, and allows the determination of down to 0.1 μg of cyanide. Most of the interferences can be avoided by displacement of the hydrogen cyanide using an arsine generator.

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References

  1. H. B. Singh, N. Wasi, M. C. Mehera,Int. J. Environ. Anal. Chem. 1986,25, 115.

    Google Scholar 

  2. W. N. Aldridge,Analyst 1944,69, 262.

    Google Scholar 

  3. APHA-AWWA-WPCF,Standard Methods for the Examination of Water and Wastewater, 14th Ed., Washington DC, 1975, p. 370.

  4. G. U. L. N. Murthy, T. S. Vishwanhan,Anal. Chim. Acta 1961,25, 293.

    Google Scholar 

  5. K. Ishii, T. Iwamato, K. Yamanishi,Bunseki Kagaku 1973,22, 448.

    Google Scholar 

  6. F. García Montelongo, M. J. Sánchez, M. A. Rodríguez, A. Francisco,Ann. Chim. (Rome) 1989,79, 59.

    Google Scholar 

  7. M. J. Sánchez, M. A. Rodríguez, F. García Montelongo,Bull. Soc. Chim. Belg. (in press).

  8. A. Tomonari,J. Chem. Soc. Japan, Pure Chem. Sect. 1962,83, 455.

    Google Scholar 

  9. W. Hinze, R. E. Humphrey,Anal. Chem. 1973,45, 385.

    Google Scholar 

  10. W. Fu-Sheng, L. Yu-Qin, Y. Fang, S. Nai-Kui,Talanta 1981,28, 694.

    Google Scholar 

  11. R. M. Dagnall, M. T. El-Ghamry, T. S. West,Talanta 1968,15, 107.

    Google Scholar 

  12. S. Nagashima,Anal. Chim. Acta 1978,99, 197.

    Google Scholar 

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García-Montelongo, F., Sánchez, M.J. & Rodríguez, M.A. Indirect spectrophotometric determination of cyanide. Mikrochim Acta 98, 259–265 (1989). https://doi.org/10.1007/BF01244602

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  • DOI: https://doi.org/10.1007/BF01244602

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