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The effect of water on the critical stress intensity factor of unsaturated polyester resins

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Abstract

The effect of water on the critical stress intensity factor,K IC, of a highly unsaturated isophthalic polyester resin has been measured for periods of immersion of up to 2200 h in water at temperatures of 35, 70 and 80° C.K IC decreased from 0.84±0.1 MN m−3/2 to 0.24±0.03 MN m−3/2 after immersion for 2200 h in water at 80° C. The observed changes in the critical stress intensity factor indicate that a constant value is eventually reached. This is consistent with the decline being attributable to the leaching of extractable matter from the polyester resin.

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References

  1. D. I. James, R. H. Norman andM. H. Stone,Plastics and Polymers 36 (1968) 21, 121.

    Google Scholar 

  2. K. H. G. Ashbee, F. C. Frank andR. C. Wyatt,Proc. Roy. Soc. A300 (1967) 415.

    Google Scholar 

  3. D. J. Steel,Trans. Plast. Inst. 35 (1967) 116, 429.

    Google Scholar 

  4. E. H. Andrews, “Fracture in Polymers” (Oliver and Boyd, London, 1968).

    Google Scholar 

  5. Idem, in “Polymer Science”, edited by A. D. Jenkins (North-Holland, London, 1972) p. 579.

    Google Scholar 

  6. C. B. Bucknall, K. V. Gotham andP. I. Vincent,ibid“, p. 621.

    Google Scholar 

  7. K. Selby andL. E. Miller,J. Mater. Sci. 10 (1975) 12.

    Google Scholar 

  8. E. H. Andrews andL. Bevan,Polymer 13 (1972) 337.

    Google Scholar 

  9. E. H. Andrews andG. M. Levy,ibid 15 (1974) 599.

    Google Scholar 

  10. Y. W. Mai,J. Mater. Sci. 10 (1975) 943.

    Google Scholar 

  11. A. D. S. Diggwa,Polymer 15 (1974) 101.

    Google Scholar 

  12. J. H. Srawley andW. F. Brown, Jun., in “Fracture Toughness Testing and Its Applications”, S.T.P. No. 381, Philadelphia (1965).

  13. M. J. Owen andR. G. Rose,J. Phys. D. 6 (1973) 42.

    Google Scholar 

  14. H. T. Corten, in “Reinforced Plastics”, edited by E. Baer (Reinhold, New York, 1964).

    Google Scholar 

  15. I. G. Romanenkov andZ. P. Machavariani,Plast. Massy. 9 (September 1966) 49.

    Google Scholar 

  16. M. Gordon andI. D. Mcmillen,Macromol. Chem. 23 (1957) 188.

    Google Scholar 

  17. G. Pritchard, Ph.D. Thesis, University of Aston in Birmingham (1968) p. 212.

  18. E. H. Erath andR. A. Spurr,J. Polymer Sci. 35 (1959) 351.

    Google Scholar 

  19. W. Funke,ibid 16 (1967) 1497.

    Google Scholar 

Download references

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Pritchard, G., Rose, R.G. & Taneja, N. The effect of water on the critical stress intensity factor of unsaturated polyester resins. J Mater Sci 11, 718–722 (1976). https://doi.org/10.1007/BF01209459

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  • DOI: https://doi.org/10.1007/BF01209459

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