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Crystal structure of bis(2,4-pentanedionato)copper(II)

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Abstract

The structure of bis(acetylacetonato)copper(II) has been redetermined from single crystal X-ray diffraction data. The unit cell parameters area=11.331(9),b=4.697(3),c=10.290(9) Å, andβ=91.84(7)dg. A finalR=0.056 for 727 observed reflections was obtained. The O-Cu-O chelate (bite) angle is 93.2(2)°. The two Cu-O bond lengths are 1.914(4) and 1.912(4) Å. The complex has a slight chair structure and a step angle of 7.05°.

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Authors and Affiliations

  1. Department of Chemistry, The University of Akron, 44325, Akron, Ohio

    P. C. Lebrun, W. D. Lyon & H. A. Kuska

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  1. P. C. Lebrun
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  2. W. D. Lyon
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  3. H. A. Kuska
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Lebrun, P.C., Lyon, W.D. & Kuska, H.A. Crystal structure of bis(2,4-pentanedionato)copper(II). Journal of Crystallographic and Spectroscopic Research 16, 889–893 (1986). https://doi.org/10.1007/BF01188194

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  • DOI: https://doi.org/10.1007/BF01188194

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