Skip to main content
Log in

A spin-trap ESR study of the homolytic decomposition of sulfonyl halides

  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

Electron spin resonance studies using 2-methyl-2-nitrosopropane and phenyl-tert-butylnitron as spin traps have been carried out on the homolytic breakdown of ethanesulfochloride, sulfuryl chloride, sulfuryl fluorochloride and benzosulfohalides of the form PhSO2X (X=Cl, F, Br).

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

Literature cited

  1. R. T. van Aller, R. B. Scott, and E. L. Brockelbank, J. Org. Chem.,31, 2357 (1966).

    Google Scholar 

  2. H. F. Herbrandson, W. S. Kelly, and J. Versnel, J. Am. Chem. Soc.,80, 3301 (1958).

    Google Scholar 

  3. R. G. Gasanov, I. I. Kandror, and R. Kh. Freidlina, Tetrahedron Lett., 1485 (1975).

  4. S. Lagercrantz, J. Phys. Chem.,75, 3466 (1971).

    Google Scholar 

  5. M. Kobayashi, E. Akiyama, H. Minato, and K. Kito, Bull. Chem. Soc., Jpn.,47, 1504 (1974).

    Google Scholar 

  6. E. G. Janzen, B. R. Knauer, L. T. Williams, and W. B. Harrison, J. Phys. Chem.,74, 3025 (1970).

    Google Scholar 

  7. E. G. Janzen and B. J. Blackburn, J. Am. Chem. Soc.,91, 4481 (1969).

    Google Scholar 

  8. H. J. Schumacher and J. Stauff, Die Chemie,55, 341 (1942); M. A. Smook, E. T. Pietski, and C. F. Hammer, Ind. and Eng. Chem.,45, 2731 (1953).

    Google Scholar 

  9. R. G. Gasanov, I. I. Kandror, and R. Kh. Freidlina, Dokl. Akad. Nauk SSSR,226, 342 (1976).

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 3, pp. 550–553, March, 1977.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Kandror, I.I., Gasanov, R.G. & Freidlina, R.K. A spin-trap ESR study of the homolytic decomposition of sulfonyl halides. Russ Chem Bull 26, 493–496 (1977). https://doi.org/10.1007/BF01179451

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF01179451

Keywords

Navigation