Abstract
The reaction of triphenylsufonium trifluoromethanesulfonate with various nucleophilic, organolithium reagents gave ligand coupling products and the corresponding diaryl or di-heteroaryl sulfides. Moreover, ligand exchange reaction did not give any noticeable product in each reaction. Therefore, it was found that only the ligand coupling reaction proceeds in this reaction system.
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References
S. Oae, T. Yoshimura, and N. Furukawa, Bull. Chem. Soc. Jpn.,45, 2019 (1972).
S. Oae, Croat, Chem. Acta,59, 129 (1986); S. Oae, Phosphorus and Sulfur,27, 13 (1986).
S. Oae, Rev. Heteroatom Chem., Tokyo,4, 195 (1991).
S. Oae, Rev. Heteroatom Chem., Tokyo,1, 304 (1988).
S. Oae and Y. Uchida, Accounts of Chem. Res.,24, 202 (1991).
Y. H. Khim and S. Oae, Bull. Chem. Soc. Jpn.,42, 1968 (1969).
R. W. LaRochelle and B. M. Trost, J. Am. Chem. Soc.,93, 6077 (1971).
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Published in Khimiya Geterotsiklicheskikh Soedinenii, No. 8, pp. 1053–1058,. August, 1995. Original article submitted August 19, 1995.
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Oae, S., Ishihara, H. & Yoshihara, M. Reaction of triphenylsulfonium salt with organolithium reagents. Chem Heterocycl Compd 31, 917–921 (1995). https://doi.org/10.1007/BF01170319
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DOI: https://doi.org/10.1007/BF01170319