Skip to main content
SpringerLink
Log in

FTIR and Raman spectral study of the preparation of lead zirconate (PbZrO3) by a solgel process in a non-flowing air atmosphere

  • Published:
Journal of Materials Science Aims and scope Submit manuscript

Abstract

Lead zirconate (PZ) materials were prepared by a sol-gel process in a non-flowing air atmosphere with no continuous agitation using lead acetate and zirconium propoxide in methoxyethanol as the precursor materials. Fourier transform infrared and Raman spectroscopy were used to characterize the structural changes that occurred during various stages of this preparation. Crystalline phase formation differences were noted during this sol-gel preparation for PZ in comparison to those occurring during the related preparation for lead titanate (PT). Metallic lead and lead oxide (PbO) were formed during the heating steps of this process in an air atmosphere for PZ.In situ Raman spectra were also measured at higher temperatures for the resulting sol-gel prepared PbZrO3 material in order to investigate its phase-transition and soft-mode behaviour.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Shu Li, R. A. Condrate Sr andR. M. Spriggs,J. Spectrosc. Lett. 21 (1988) 969.

    Google Scholar 

  2. Shu Li, MS thesis, Alfred University. Alfred, New York (1988).

    Google Scholar 

  3. A. E. Pasto andR. A. Condrate Sr, “Advances in Raman Spectroscopy”, Vol. 1. edited by J. P. Mathieu, (Heyden, London 1973) p. 196.

    Google Scholar 

  4. Idem, J. Amer. Ceram. Soc. 56 (1973) 436.

    Google Scholar 

  5. W. Cochran andA. Zia,Phys. Status Solidi 25 (1968) 273.

    Google Scholar 

  6. G. Shirane andY. Yammada,Phys. Rev. 177 (1969) 858.

    Google Scholar 

  7. G. A. Samara,Phys. Rev. B 1 (1970) 3777.

    Google Scholar 

  8. K. K. Mani andS. N. Shringi,Phys. Status Solidi 44 (1971) K49.

    Google Scholar 

  9. G. F. Pan'ko, V. V. Prisedskit andV. V. Klimov,Sov. Phys. Solid State 25 (1983) 2111.

    Google Scholar 

Download references

Author information

Author notes

  1. S. D. Jang

    Present address: Korea Institute of Science and Technology, Seoul, Korea

Authors and Affiliations

  1. Center for Advanced Ceramic Technology, New York State College of Ceramics, Alfred University, 14802, Alfred, New York, USA

    Shu Li, R. A. Condrate Sr, S. D. Jang & R. M. Spriggs

Authors
  1. Shu Li
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. R. A. Condrate Sr
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. S. D. Jang
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. R. M. Spriggs
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Li, S., Condrate, R.A., Jang, S.D. et al. FTIR and Raman spectral study of the preparation of lead zirconate (PbZrO3) by a solgel process in a non-flowing air atmosphere. J Mater Sci 24, 3873–3877 (1989). https://doi.org/10.1007/BF01168949

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF01168949

Keywords

Search

Navigation