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Reactivity of the fluoride ion in polar aprotic solvents

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    A kinetic study was carried out on the reaction of fluoride ion with O,S-diethyl methylphosphonate in polar, aprotic solvents which enhance the reactivity of the fluoride ion.

  2. 2.

    Regression equations were obtained which permit prediction of the reactivity of the fluoride ion in different solvents relative to the rate constants of reactions with anionic nucleophiles.

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Authors and Affiliations

  1. A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Branch, Academy of Sciences of the USSR, USSR

    V. E. Bel'skii & G. S. Sakulin

Authors
  1. V. E. Bel'skii
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  2. G. S. Sakulin
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 1, pp. 215–217, January, 1985.

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Bel'skii, V.E., Sakulin, G.S. Reactivity of the fluoride ion in polar aprotic solvents. Russ Chem Bull 34, 204–205 (1985). https://doi.org/10.1007/BF01157360

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  • DOI: https://doi.org/10.1007/BF01157360

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