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Microanalysis of the surface in glass-ceramics obtained from muscovite-amblygonite

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Abstract

A new family of glass-ceramics obtained from muscovite-amblygonite mixtures showing a schiller effect or reflecting surface has been obtained. This effect has not been observed in the bulk material. The raw materials contain about 1% iron as Fe21. In order to elucidate the correlation between surface structure and/or composition and the schiller surface effect, several surface analysis methods, (ESCA, RBS, EPR and reflection Mössbauer spectroscopy) have been used. It seems that a solid solution of Fe31 in the spodumene crystal lattice precipitated from the surface is related to the reflecting effect, which can be controlled by solution of iron oxides in theβ-spodumene solid solution.

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  1. Instituto de Cerámica y Vidrio, CSIC, Arganda del Rey, Madrid, Spain

    J. Má Rincón & P. Callejas

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  1. J. Má Rincón
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  2. P. Callejas
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Rincón, J.M., Callejas, P. Microanalysis of the surface in glass-ceramics obtained from muscovite-amblygonite. J Mater Sci 23, 1042–1049 (1988). https://doi.org/10.1007/BF01154009

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  • DOI: https://doi.org/10.1007/BF01154009

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