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Synthesis of unsaturated 7,8- and 7,9-di(hydroxymethyl)decahydro-7,8- and-7,9-dicarba-nido-undecaborate(1−) diethers

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Abstract

Dicarba-nido-undecaborate(1−) anions were obtained by treatment of 1,2-di(hydroxymethyl)-1,2-dicarba-closo-dodecaborane(12) diallyl ether, 1,2-di(hydroxymethyl)-1,2-dicarba-closo-dodecaborane (12), and 1,7-di(hydroxymethyl)-1,7-dicarba-closo-dodecaborane(12) with ethanolic solutions of KOH and subsequent reaction of the products with cesium and tetramethylammonium chlorides.

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 117813, Moscow, Russian Federation

    A. I. Solomatina, L. G. Komarova & A. L. Rusanov

Authors
  1. A. I. Solomatina
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  2. L. G. Komarova
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  3. A. L. Rusanov
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Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 9, pp. 1821–1823, September, 1995.

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Solomatina, A.I., Komarova, L.G. & Rusanov, A.L. Synthesis of unsaturated 7,8- and 7,9-di(hydroxymethyl)decahydro-7,8- and-7,9-dicarba-nido-undecaborate(1−) diethers. Russ Chem Bull 44, 1752–1754 (1995). https://doi.org/10.1007/BF01151305

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  • DOI: https://doi.org/10.1007/BF01151305

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