Skip to main content
Log in

Interaction between binder and powder in injection moulding of alumina

  • Papers
  • Published:
Journal of Materials Science Aims and scope Submit manuscript

Abstract

In injection moulding of alumina the binder components interacted with the alumina powder by a Lewis acid-base reaction. Among the binder components used, stearic acid played a major role in determining the process behaviour even though its composition was only 4 wt% of the total binder (1.8 vol% of the formulation including powder). The effects of the chemisorbed stearic acid due to the Lewis acid-base interaction were a reduction of the apparent viscosity by a factor of 20, minimized separation of binder from the powder during moulding, but a higher content of binder burnout residue than in the carbonyl-iron system.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. R. M. German, in “Powder injection molding” (Metal Powder Industries Federation, Princeton, NJ, 1990) p. 5.

    Google Scholar 

  2. R. M. German, K. F. Hens andS. T. Lin,Bull. Amer. Ceram. Soc. 70 (1991) 1294.

    Google Scholar 

  3. K. F. Hens, D. Lee, S. T. Lin andR. M. German Powder Metallurgy Int. 23 (1990) 15.

    Google Scholar 

  4. M. D. Sacks, C. S. Khadilkar, G. W. Scheiffele, A. V. Shenoy, J. H. Dow andR. S. Sheu, in “Ceramic powder science”, edited by G. L. Messing, K. S. Kazdiyasni, J. W. McCauley and R. A. Harber (American Ceramic Society, OH, 1987) p. 495.

    Google Scholar 

  5. M. T. Martyn, R. J. James, andB. Haworth,Metal Powder Report 43 (1988) 816.

    Google Scholar 

  6. F. M. Fowkes, in “Ceramic powder science”, edited by G. L. Messing, K. S. Kazdiyasni, J. W. McCauley and R. A. Harber (American Ceramic Society, OH, 1987) p. 411.

    Google Scholar 

  7. J. G. Zhang, M. J. Edirisinghe andJ. R. G. Evans,J. Mater. Sci. 23 (1988) 2115.

    Google Scholar 

  8. Y. N. Sun, M. D. Sacks andJ. W. Williams, in “Ceramic powder science II” Vol. I, Part A, edited by G. L. Messing, E. R. Fuller Jr and H. Hausner (American Ceramic Society, OH, 1988) p. 538.

    Google Scholar 

  9. K. E. Howard, C. D. E. Lakeman andD. A. Payne,J. Amer. Ceram. Soc. 73 (1990) 2543.

    Google Scholar 

  10. M. Green, T. Kramer, M. Parish, J. Fox, R. Lalanandham, W. Rhine, S. Barclay, P. Calvert andH. K. Bowen, in “Ceramic powder science”, edited by G. L. Messing, K. S. Kazdiyasni, J. W. McCauley and R. A. Harber (American Ceramic Society, OH, 1987) p. 449.

    Google Scholar 

  11. K. Lindqvist, E. Carlstrom, M. Persson andR. Carlsson,J. Amer. Ceram. Soc. 72 (1989) 99.

    Google Scholar 

  12. M. J. Edirisinghe,Ceram. Int. 17 (1991) 89.

    Google Scholar 

  13. Idem, J. Mat. Sci. Lett. 9 (1990) 1039.

    Google Scholar 

  14. J. S. Reed, in “Introduction to the principles of ceramic processing” (John Wiley & Sons, New York, 1988) p. 134.

    Google Scholar 

  15. R. O. James, in “Ceramic powder science”, edited by G. L. Messing, K. S. Kazdiyasni, J. W. McCauley and R. A. Harber (American Ceramic Society, OH, 1987) p. 349.

    Google Scholar 

  16. R. H. Yoon, T. Salman andG. Donnay,J. Colloid Interface Sci. 70 (1979) 483.

    Google Scholar 

  17. F.W. Fowkes andD. O. Tischler,J. Polym. Sci. Polym. Chem. Edn 22 (1984) 547.

    Google Scholar 

  18. T. K. Kwei, E. M. Pearce, F. Ren andJ. P. Chen,J. Polym. Sci. B, Polym. Phys. 24 (1986) 1597.

    Google Scholar 

  19. E. M. Deliso, A. S. Rao andW. R. Cannon, in “Ceramic powder science”, edited by G. L. Messing, K. S. Kazdiyasni, J. W. McCauley and R. A. Harber (American Ceramic Society, OH, 1987) p. 525.

    Google Scholar 

  20. R. E. Wiech, US Patent # 4,661,315, April (1987).

  21. H. Bennet, in “Industrial wax”, Vol. I (Chemical Publishing Company Inc., New York, 1963) p. 43.

    Google Scholar 

  22. S.T. Lin andR. M. German,Powder Metall. Int. 21 (1989) 19.

    Google Scholar 

  23. T. S. Wei andR. M. German,Int. J. Powder Metall 24 (1988) 327.

    Google Scholar 

  24. H. H. Willard, L. L. Merritt Jr,J. A. Dean andF. A. Settle Jr, in “Instrumental methods of analysis”, 6th Edn (D. Van Nostrand Company, New York, 1981) p. 148.

    Google Scholar 

  25. A. L. Smith, in “Applied infrared spectroscopy, fundamentals, techniques, and analytical problem-solving” (John Wiley & Sons, New York, 1979) p. 287.

    Google Scholar 

  26. J. K. Wright, J. R. G. Evans andM. J. Edirisinghe,J. Amer. Ceram. Soc. 72 (1989) 1822.

    Google Scholar 

  27. H. Schonhorn,J. Polym. Sci. A 1 (196) 2335.

  28. J. G. Zhang, M. J. Edirisinghe andJ. R. G. Evans,Ind. Ceram. 9 (1989) 72.

    Google Scholar 

  29. Y. Suetsugu andJ. L. White,J. Appl. Polym. Sci. 28 (1983) 1481.

    Google Scholar 

  30. B. J. Carpenter, M.S. Thesis, Rensselaer Polytechnic Institute, Troy, NY (1988).

    Google Scholar 

  31. M. J. Edirisinghe, H. M. Shaw andK. L. Tomkins,Ceram. Int. 18 (1992) 193.

    Google Scholar 

  32. S. T. Paul Lin, PhD Thesis, Rensselaer Polytechnic Institute, Troy, NY (1991).

    Google Scholar 

  33. B. O. Rhee, M. Y. Cao, H. R. Zhang andC. I. Chung, presented at MPIF, APMI Powder Metallurgy Conference and Exhibition, June, 1991, Chicago, IL.

  34. W. K. Shih, M. D. Sacks, G. W. Scheiffele, Y. N. Sun andJ. W. Williams, in “Ceramic powder science II,” Vol. I, Part A, edited by G. L. Messing, E. R. Fuller Jr and H. Hausner (American Ceramic Society, OH, 1988) p. 549.

    Google Scholar 

  35. S. T. Lin, R. M. German, K. F. Hens andD. Lee, in “Advances in powder metallurgy”, Vol. 3, edited by E. R. Andreotti and P. J. McGeehan (Metal Powder Industries Federation, NJ, 1990) p. 423.

    Google Scholar 

  36. F. J. Klung, W. D. Pasco andM. P. Borom,J. Amer. Ceram. Soc. 65 (1982) 619.

    Google Scholar 

  37. M. V. Boddu andD. S. Viswanath,J. Amer. Ceram. Soc. 73 (1990) 1620.

    Google Scholar 

  38. D. R. Gaskell, in “Introduction to metallurgical thermodynamics” (McGraw Hill Book Company, New York, 1981) p. 585.

    Google Scholar 

  39. S. Masia, P. D. Calvert, W. E. Rhine andH. K. Bowen,J. Mater. Sci. 24 (1989) 1907.

    Google Scholar 

  40. J. R. G. Evans andM. J. Edirisinghe,J. Mater. Sci. 26 (1991) 2081.

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Lin, S.T., German, R.M. Interaction between binder and powder in injection moulding of alumina. J Mater Sci 29, 5207–5212 (1994). https://doi.org/10.1007/BF01151118

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF01151118

Keywords

Navigation