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Processing of cellulose via highly concentrated “solid solutions”

  • New Methods of Fabrication of Cellulose Fibres
  • Published:
Fibre Chemistry Aims and scope

Abstract

The examined method of processing cellulose can be used to conduct solid-phase EDA-complexation of cellulose with high-melting MMO hydrates in conditions of the effect of shear strains and pressure. The method allows: expanding the concentration range of the solubility of cellulose in MMO to 50% and obtaining highly concentrated spinning solutions with a concentration of up to 30%; decreasing the duration of dissolution to 5–10 min; regulating the process of thermal degradation of MMO and cellulose: fabricating “Orcel®” fibre with a high degree of orientation and high strength and modulus of elasticity. The solid-phase amine oxide method of processing cellulose was developed by the contract group at the All-Russian Scientific-Research Institute of Polymer Fibres (VNIIPV): Candidate L. K. Golova (director), candidate N. V. Vasil'eva, Candidate L. K. Kuznetsova. Candidate T. A. Lyubova, Research Associate O. E. Borodina, and Research Associate T. B. Krylova with the participation of leading specialists at the Institute's BI Center (director of the Center, Candidate I. Z. Eifer). The studies of the properties and structure of Orcel® fibre were conducted by leading specialists at the Institute's BIFIM Complex (Professor M. M. Iovleva. Director). Candidates V. N. Smirnova, S. I. Banduryan, T. A. Belousova, L. P. Mil'kova, I. N. Andreeva, L. P. Konovalova, V. G. Brusentsova, Dr. A. T. Kalashnik, Research Associate G. Ya. Rudinskaya, and Dr. A. Sh. Goikhman.

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Authors
  1. L. K. Golova
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Additional information

All-Russian Scientific-Research Institute of Polymer Fibres, Mytishchi. Translated from Khimicheskie Volokna, No. 1, pp. 13–23, January–February, 1996.

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Golova, L.K. Processing of cellulose via highly concentrated “solid solutions”. Fibre Chem 28, 5–16 (1996). https://doi.org/10.1007/BF01130691

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