Abstract
A Couette-type concentric cylinder apparatus to investigate liquids at equilibrium and under shear has been constructed and tested. The apparatus is designed for a neutron facility and is optimized as a general purpose adjunct to the small-angle neutron scattering (SANS) equipment. It is versatile and rugged; a wide range of shear rates and operating temperatures can be covered; and controls are fully automated. Test results with sheared colloidal suspensions of 91-nm polystyrene spheres are presented. Evidence of shear-induced structure changes is clear.
Similar content being viewed by others
References
G. C. Straty,NIST J. Res. 94:259 (1989).
P. Lindner and R. C. Oberthur,Rev. Phys. Appl. 19:759 (1984).
S.-H. Chen and T.-S. Lin, inMethods in Experimental Physics, Vol. 23, Part B,Neutron Scattering (Academic Press, London, 1987); R. H. Ottewill, inColloidal Dispersions (Royal Society Chem. Special Publication, No. 43, 1982).
C. J. Glinka, D. A. Aaustuen, H. J. M. Hanley, and G. C. Straty, unpublished data (1989) [available from the Thermophysics Division, NIST, Boulder, 80303].
E. B. Sirota, H. D. Ou-Yang, S. K. Sinha, P. M. Chaikin, J. D. Axe, and Y. Fujii,Phys. Rev. Lett. 62:1524 (1989).
R. L. Hoffman,Trans. Soc. Rheol. 16:155 (1972).
B. J. Ackerson and N. A. Clark,Physica 118a:221 (1983).
B. J. Ackerson, J. B. Hayter, N. A. Clark, and L. Cotter,J. Chem. Phys. 84:2344 (1986).
H. J. M. Hanley, inLectures on Thermodynamics and Statistical Mechanics, A. E. Gonzales and C. Varea, eds. (World Scientific, Singapore, 1988).
H. J. M. Hanley, J. C. Rainwater, N. A. Clark, and B. J. Ackerson,J. Chem. Phys. 79:4448 (1983).
B. J. Ackerson and P. N. Pusey,Phys. Rev. Lett. 61:1033 (1989); B. J. Ackerson, C. G. de Kruif, N. J. Wagner, and W. B. Russel,J. Chem. Phys. 90:3250 (1989).
N. J. Wagner and W. B. Russel, Unpublished data (1989).
S. J. Johnson, C. G. De Kruiff, and R. P. May,J. Chem. Phys. 89:5909 (1988).
C. J. Glinka, J. M. Rowe, and J. G. LaRock,J. Appl. Cryst. 19:427 (1986).
Author information
Authors and Affiliations
Additional information
Work carried out at the National Institute of Standards and Technology, not subject to copyright.
Rights and permissions
About this article
Cite this article
Straty, G.C., Hanley, H.J.M. & Glinka, C.J. Shearing apparatus for neutron scattering studies on fluids: Preliminary results for colloidal suspensions. J Stat Phys 62, 1015–1023 (1991). https://doi.org/10.1007/BF01128174
Received:
Revised:
Issue Date:
DOI: https://doi.org/10.1007/BF01128174