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IR spectra and structures of tellurite glasses

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Abstract

It is shown with IR spectral investigations that the short range order of certain tellurite glasses, obtained from monomineral crystalline phases, is similar to that of the crystals. They may contain the following polyhedra: TeO4-trigonal bipyramids (C2v symmetry), deformed TeO4 groups, TeO3 trigonal pyramids (C3v point symmetry), or combinations of these polyhedra. The introduction of V2O5 and MoO3 in the binary glasses leads to a TeO4 → TeO3 transition. MoO3 delays the decay of TeO4 groups in a wider concentration range.

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References

  1. M. Arnaudov, V. Dimitrov andY. Dimitriev,Mater. Res. Bull. 17 (1982) 1121.

    Google Scholar 

  2. A. K. Yakhkind, in “Structure i fizikochimitsheskie svoistva neorganitsheskich stekol”, edited by A. G. Vlasov and V. A. Florinska (Chimia, Leningrad, 1974) p. 67.

    Google Scholar 

  3. N. Mochida, K. Takahashi, K. Nakata andS. Shibusawa,Yoguo-Kuokai-Shi. 86 (1978) 317.

    Google Scholar 

  4. Y. Dimitriev, M. Arnaudov andV. Dimitrov,Mh. Chem. 107 (1976) 1335.

    Google Scholar 

  5. Y. Dimitriev, V. Dimitrov andM. Arnaudov,J. Mater. Sci. 14 (1979) 723.

    Google Scholar 

  6. Y. Dimitriev, J. C. J. Bart, V. Dimitrov andM. Arnaudov,Z. Anorg. Allg. Chem. 479 (1981)

  7. P. Tarte,Spectrochim. Acta 18 (1962) 467.

    Google Scholar 

  8. P. Tarte, in “Physics of Non-Crystalline Solids”, edited by J. A. Prins (North Holland, Amsterdam, 1964) p. 549.

    Google Scholar 

  9. H. Siebert, “Anwendungen der Schwingungsspektroskopie in der Anorganischen Chemie” (Springer. Berlin, 1966).

    Google Scholar 

  10. R. A. Condrat, in “Introduction to Glass Science”, edited by L. D. Pye, H. J. Stevens and W. C. Lacourse (Plenum Press, New York, London, 1972) p. 101.

    Google Scholar 

  11. O. Lindqvist,Acta Chem. Scand. 22 (1968) 977.

    Google Scholar 

  12. J. Galy, G. Meunier, S. Andersson andA. Aström,J. Solid State Chem. 13 (1975) 142.

    Google Scholar 

  13. R. J. Gillespie, “Molecular Geometry” (Van Nostrand Reinhold Company, London, 1972).

    Google Scholar 

  14. Y. Dimitriev, E. Gateff, E. Kashchieva andV. Dimitrov, Proceedings of the 11th International Congress on Glass, Prague 1, edited by J. Gotz (1977) p. 159.

  15. V. Dimitrov, thesis, Sofia (1978).

  16. Y. Dimitriev andV. Dimitrov,Mater. Res. Bull. 13 (1978) 1071.

    Google Scholar 

  17. Y. Dimitriev, V. Dimitrov andM. Arnaudov,Mh. Chem. 109 (1978) 791.

    Google Scholar 

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Authors and Affiliations

  1. Higher Institute of Chemical Technology, 1156, Sofia, Bulgaria

    Y. Dimitriev & V. Dimitrov

  2. ‘Kliment Ochridsky’ University, Sofia, Bulgaria

    M. Arnaudov

Authors
  1. Y. Dimitriev
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  2. V. Dimitrov
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  3. M. Arnaudov
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Dimitriev, Y., Dimitrov, V. & Arnaudov, M. IR spectra and structures of tellurite glasses. J Mater Sci 18, 1353–1358 (1983). https://doi.org/10.1007/BF01111954

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  • DOI: https://doi.org/10.1007/BF01111954

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