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Structural study of semiconducting and superionic conducting silver vanadate glasses

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Abstract

A structural study of semiconducting and superionic conducting silver vanadate glasses, containing 40 mol% Agl and 1 mol %57Fe2O3, is performed by means of Mössbauer spectroscopy. Distinct composition dependency of Mössbauer parameters (Δ and Γ) of Fe3+ ions, having a minimum when Ag2O content is 30 mol %, suggests that increasing Ag2O content results in a gradual change of the glass matrix from a two-dimensional layer structure composed of VO5 tetragonal pyramids to a chain structure composed of VO4 tetrahedra. An increase in the Mössbauer parameters observed when the Ag2O content is higher than 30 mol %, corresponding to a metavanadate structure (Ag2O/V2O5=1), indicates a reverse change of the glass matrix into a complicated two- or three-dimensional network structure composed of VO4 tetrahedra. These conclusions are in good agreement with those obtained from a distinct composition dependency of glass transition temperatures (T g). Composition dependency of electrical conductivity at room temperature suggests that the structural change of glass matrix primarily affects the semiconductivity caused by a step-by-step electron hopping from V4+ to V5+ ions.

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References

  1. T. Minami, Y. Takura andM. Tanaka,J. Electrochem. Soc. 124 (1977) 1659.

    Google Scholar 

  2. T. Minami andM. Tanaka,J. Non-Cryst. Solids 38/39 (1980) 289.

    Google Scholar 

  3. T. Minami, K. Imazawa andM. Tanaka,ibid. 42 (1980) 469.

    Google Scholar 

  4. A. Fontana, G. Mariotto, E. Cazzanelli, G. Carini, M. Cutroni andM. Federico,Phys. Lett. 93A (1983) 209.

    Google Scholar 

  5. G. Dalba, A. Fontana, P. Fornasini, G. Mariotto, M. R. Masullo andF. Rocca,Solid State Ionics 9/10 (1983) 597.

    Google Scholar 

  6. J. P. Malugani andR. Mercier,ibid. 13 (1984) 293.

    Google Scholar 

  7. G. Chiodelli, G. Camparivigano, G. Flor, A. Magistris andM. Villa,ibid. 8 (1983) 311.

    Google Scholar 

  8. K. Matusita andS. Sakka,Yogyo-Kyokai-Shi 84 (1976) 496.

    Google Scholar 

  9. T. Tsuchiya, T. Horiuchi andT. Moriya,ibid. 87 (1979) 223.

    Google Scholar 

  10. H. Hirashima, M. Mitsuhashi andT. Yoshida,ibid. 90 (1982) 411.

    Google Scholar 

  11. H. Hirashima, K. Nishii andT. Yoshida,J. Amer. Ceram. Soc. 66 (1983) 704.

    Google Scholar 

  12. T. Yoshida, H. Hirashima andM. Kato,YogyoKyokai-Shi 93 (1985) 244.

    Google Scholar 

  13. E. M. Milan,J. Phys. Chem. 38 (1929) 498.

    Google Scholar 

  14. J. H. deBoer andE. J. W. Verway,Proc. Phys. Soc. (London) Suppl. 49 (1937) 59.

    Google Scholar 

  15. G. L. Sewell,Phys. Rev. 129 (1963) 597.

    Google Scholar 

  16. T. Allersma, R. Hakim, T. N. Kennedy andJ. D. Mackenzie,J. Chem. Phys. 46 (1967) 154.

    Google Scholar 

  17. N. F. Mott,Adv. Phys. 16 (1967) 49.

    Google Scholar 

  18. Idem, J. Non-Cryst. Solids 1 (1968) 1.

    Google Scholar 

  19. I. G. Austin andN. F. Mott,Adv. Phys. 18 (1969) 41.

    Google Scholar 

  20. A. Byström, K. A. Wilhelmi andO. Brotzen,Acta Chem. Scand. 4 (1950) 1119.

    Google Scholar 

  21. K. Jansen andG. Sperlich,Phys. Status Solidi (b) 55 (1973) 495.

    Google Scholar 

  22. Y. Dimitriev, V. Dimitrov, M. Arnaudov andD. Topalov,J. Non-Cryst. Solids 57 (1983) 147.

    Google Scholar 

  23. S. L. Segel andR. B. Creel,Can. J. Phys. 48 (1970) 2673.

    Google Scholar 

  24. A. C. Wright, C. A. Yarker, P. A. V. Johnson andR. N. Sinclair,J. Non-Cryst. Solids 76 (1985) 333.

    Google Scholar 

  25. S. Stizza, I. Davoli, O. Gzowski, L. Murawski, M. Tomellini, A. Marcelli andA. Bianconi,ibid. 80 (1986) 175.

    Google Scholar 

  26. F. R. Landsberger andP. J. Bray,J. Chem. Phys. 53 (1970) 2757.

    Google Scholar 

  27. L. G. Bogomolova, M. P. Glassova, O. E. Budatovko, S. I. Reiman andS. N. Spasibkina,J. Non-Cryst. Solids 58 (1983) 71.

    Google Scholar 

  28. A. K. Bandyopadhyay, M. Ribes, F. Pernot andJ. Zarzycki,Phys. Chem. Glasses 23 (1982) 31.

    Google Scholar 

  29. T. K. Bansal, N. Kishore andR. G. Mendiratta,ibid. 26 (1985) 94.

    Google Scholar 

  30. D. K. Kanchan, R. K. Puri andR. G. Mendiratta,ibid. 26 (1985) 217.

    Google Scholar 

  31. C. R. Kurkjian,J. Non-Cryst. Solids 3 (1970) 157.

    Google Scholar 

  32. J. M. D. Coey,J. Phys. 35 (1974) C6–89.

    Google Scholar 

  33. W. Müller-Warmuth andH. Eckert,Phys. Rep. 88 (1982) 91.

    Google Scholar 

  34. N. N. Greenwood andT. C. Gibb, in “Mössbauer Spectroscopy” (Chapman and Hall, London, 1971) Ch. 3.

    Google Scholar 

  35. R. Ingalls, F. Van Der Woude andG. A. Sawatzky, in “Mössbauer Isomer Shifts”, edited by G. K. Shenoy and F. E. Wagner (North-Holland, Amsterdam, 1978) Ch. 7.

    Google Scholar 

  36. T. Nishida andY. Takashima,J. Non-Cryst. Solids 37 (1980) 37.

    Google Scholar 

  37. T. Nishida, Y. Takashima andY. Nakayama,J. Solid State Chem. 33 (1980) 141.

    Google Scholar 

  38. T. Nishida, T. Shiotsuki andY. Takashima,J. Non-Cryst. Solids 41 (1980) 161.

    Google Scholar 

  39. T. Nishida, T. Hirai andY. Takashima,ibid. 43 (1981) 221.

    Google Scholar 

  40. T. Nishida, N. Kai andY. Takashima,Phys. Chem. Glasses 22 (1981) 107.

    Google Scholar 

  41. T. Nishida, T. Nonaka, T. Isobe andY. Takashima,ibid. 24 (1983) 88.

    Google Scholar 

  42. T. Nishida andY. Takashima, in “Industrial Applications of the Mössbauer Effect”, edited by G. J. Long and J. G. Stevens (Plenum Press, New York, London, 1986) Ch. 21.

    Google Scholar 

  43. T. Nishida, T. Hirai andY. Takashima,Phys. Chem. Glasses 22 (1981) 94.

    Google Scholar 

  44. Idem, Bull. Chem. Soc. Jpn 54 (1981) 3735.

    Google Scholar 

  45. M. F. Taragin, J. C. Eisenstein andW. Haller,Phys. Chem. Glasses 13 (1972) 149.

    Google Scholar 

  46. T. Nishida, T. Shiotsuki andY. Takashima,J. Non-Cryst. Solids 43 (1981) 115.

    Google Scholar 

  47. Idem, ibid. 43 (1981) 123.

    Google Scholar 

  48. T. Nishida, Y. Miyamoto andY. Takashima,Bull. Chem. Soc. Jpn 56 (1983) 439.

    Google Scholar 

  49. E. M. Boulos andN. J. Kreidl,J. Amer. Ceram. Soc. 54 (1971) 368.

    Google Scholar 

  50. J. E. Shelby,ibid. 57 (1974) 436.

    Google Scholar 

  51. Idem, J. Appl. Phys. 46 (1975) 193.

    Google Scholar 

  52. R. M. Almeida andJ. D. Mackenzie,J. Chem. Phys. 74 (1981) 5954.

    Google Scholar 

  53. T. Nishida, M. Katada andY. Takashima,Bull. Chem. Soc. Jpn 57 (1984) 3566.

    Google Scholar 

  54. J. L. Piguet andJ. E. Shelby,J. Amer. Ceram. Soc. 68 (1985) 450.

    Google Scholar 

  55. T. Nishida, T. Nonaka andY. Takashima,Bull. Chem. Soc. Jpn 58 (1985) 2255.

    Google Scholar 

  56. T. Nishida andY. Takashima,ibid. 59 (1986) 2789.

    Google Scholar 

  57. T. Nishida, M. Ogata andY. Takashima,ibid. 59 (1986) 2401.

    Google Scholar 

  58. Idem, ibid. 60 (1987) 2381.

    Google Scholar 

  59. Idem, Phys. Chem. Glasses 29 (1988) 22.

    Google Scholar 

  60. T. Nishida andY. Takashima,Bull. Chem. Soc. Jpn 60 (1987) 941.

    Google Scholar 

  61. T. Nishida, M. Ogata andY. Takashima,ibid. 60 (1987) 2887.

    Google Scholar 

  62. Idem, J. Non-Cryst. Solids 95/96 (1987) 241.

    Google Scholar 

  63. T. Nishida, S. Saruwatari andY. Takashima,Bull. Chem. Soc. Jpn 61 (1988) 2343.

    Google Scholar 

  64. T. Nishida andY. Takashima,J. Non-Cryst. Solids 94 (1987) 229.

    Google Scholar 

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Science, Kyushu University, 33, Hakozaki, Higashiku, 812, Fukuoka, Japan

    Tetsuaki Nishida, Hiroshi Ide & Yoshimasa Takashima

  2. Department of Physics, Faculty of Science, Kyushu University, 33, Hakozaki, Higashiku, 812, Fukuoka, Japan

    Toshirou Yagi, Satoru Tomariguchi, Tohru Ishizuka & Akira Sakai

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  1. Tetsuaki Nishida
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  2. Hiroshi Ide
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  3. Yoshimasa Takashima
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  4. Toshirou Yagi
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  5. Satoru Tomariguchi
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  6. Tohru Ishizuka
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  7. Akira Sakai
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Nishida, T., Ide, H., Takashima, Y. et al. Structural study of semiconducting and superionic conducting silver vanadate glasses. J Mater Sci 24, 1687–1692 (1989). https://doi.org/10.1007/BF01105692

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  • DOI: https://doi.org/10.1007/BF01105692

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