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Study of binuclear copper(II) complexes involving bridging Schiff bases—I

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Summary

The synthesis of binuclear complexes obtained by the reaction of aromatic diamines with the ternary complexes of copper(II) with bis(2-pyridyl)amine (dpa) as primary ligand and salicylaldehyde or 2-hydroxynaphthaldehyde as secondary ligand have been reported. The complexes have been characterized by elemental analyses, conductance, electronic and i.r. spectral studies. Magnetic measurements indicate antiferromagnetic exchange between two copper(II) centres. E.s.r. spectra exhibit a ΔMs=2 transition, supporting the antiferromagnetic coupling.

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Science, M. S. University of Baroda, 390 002, Baroda, India

    Neelima D. Kulkarni & Pabitra K. Bhattacharya

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  1. Neelima D. Kulkarni
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  2. Pabitra K. Bhattacharya
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Kulkarni, N.D., Bhattacharya, P.K. Study of binuclear copper(II) complexes involving bridging Schiff bases—I. Transition Met Chem 14, 303–305 (1989). https://doi.org/10.1007/BF01098235

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