Abstract
Phosphate sorption curves give useful information about the management of the P fertility in soils. This study was conducted to examine how P sorption characteristics were influenced, and could be predicted from the properties of Mediterranean soils of Spain. The 114 soils studied differed widely in origin and properties and were grouped as calcareous (43) and noncalcareous (71). Citrate-bicarbonate-dithionite extractable Fe (Fed) and Al (Ald) and clay were the properties best correlated with the P sorbed and the P buffer capacity at an equilibrium concentration of 0.2 mg P l−1. This suggests that Fe oxides and silicate clays play a significant role in P sorption. Stepwise regression analysis showed, however, that clay was not a significant variable in the calcareous group, but active CaCO3 was. Prediction of the P sorption parameters was better for the noncalcareous than for the calcareous group. This reduced ability to predict P sorption in calcareous soils may be due to the inability of total or active CaCO3 to adequately measure the reactivity of carbonates towards P sorption. From 53 to 75% of the variation in P sorption parameters could be explained by regression equations including all or several of the following routinely-determined soil properties: clay, pH, Fed, and active CaCO3. These equations could, therefore, provide a simple and rapid estimation of P sorption in soils of Mediterranean regions.
Similar content being viewed by others
References
Bache BW (1977) Practical implications of quantityintensity relationships. In: Proc. Int. Seminar on Soil Environment and Fertility Management in Intensive Agriculture, pp. 777–787. Tokyo, Japan: Soc. of the Science of Soil and Manure
Bache BW and Williams EG (1971) A phosphate sorption index for soils. J Soil Sci 22: 289–301
Barber SA (1984) Soil Nutrient Bioavailability: A Mechanistic Approach. New York: John Wiley & Sons
Borrero C, Peña F and Torrent J (1988) Phosphate sorption by calcium carbonate in some soils of the Mediterranean part of Spain. Geoderma 42: 261–269
Bowman RA and Olsen SR (1985) Assessment of phosphate-buffering capacity: 2. Greenhouse methods. Soil Sci 140: 387–392
Burnham CP and López-Hernández D (1982) Phosphate retention in different soil taxonomic classes. Soil Sci 134: 376–380
Fox RL (1981) External phosphorus requirements of crops. In: Stelly M (ed.) Chemistry in the Soil Environment, pp. 223–239. Madison, Wisc: American Society of Agronomy Special Publication 40
Fox RL and Kamprath EJ (1970) Phosphate sorption isotherms for evaluating the phosphate requirements of soils. Soil Sci Soc Am Proc 34: 902–907
Holford ICR (1979) Evaluation of soil phosphate buffering indices. Aust J Soil Res 18: 405–414
Holford ICR (1980) Greenhouse evaluation of four phosphorus soil tests in relation to phosphate buffering and labile phosphate in soils. Soil Sci Soc Am J 44: 555–559
Holford ICR (1988) Buffering of phosphate in the soil solution during growth of ryegrass compared with buffering by sorption. Plant and Soil 111: 3–9
Holford ICR and Cullis BR (1985) Effects of phosphate buffer capacity on yield response curvature and fertilizer requirements on wheat in relation to soil phosphate tests. Aust J Soil Res 23: 417–427
Le Mare PH (1981) Phosphorus sorption and release. In: Greenland DJ (ed.) Characterization of Soils in Relation to their Classification and Management for Crop Production: Examples from Some Areas from the Humid Tropics, pp. 97–134. New York: Oxford University Press
Loganathan P, Isirimah NO and Nwachuku DA (1987) Phosphorus sorption by Ultisols and Inceptisols of the Niger delta in southern Nigeria. Soil Sci 144: 330–338
McLean EO, Oloya TO and Adams JL (1979) Soil tests to inventory the initially available levels and to assess the fates of added P and K as bases for improved fertilizer recommendations. Commun Soil Sci Plant Anal 10: 623–630
Mehra OP and Jackson ML (1960) Iron oxide removal from soils and clays by a dithionite-citrate system buffered with sodium bicarbonate. In: Swineford A (ed.) Clays and Clay Minerals (Proc 7th Nat Conf), pp. 317–327. New York: Pergamon Press
Murphy J and Riley JP (1962) A modified single solution method for the determination of phosphate in natural waters. Anal Chim Acta 27: 31–36
Olsen SR, Cole CV, Watanabe FS and Dean LA (1954) Estimation of available phosphorus in soils by extraction with sodium bicarbonate. USDA Circ. 939. Washington: U.S. Gov Print Office
Peña F and Torrent J (1984) Relationships between phosphate sorption and iron oxides in Alfisols from a river terrace sequence of Mediterranean Spain. Geoderma 33: 283–296
Ryan J, Curtin D and Chema MA (1985) Significance of iron oxides and calcium carbonate particle size in phosphate sorption by calcareous soils. Soil Sci Soc Am J 49: 74–76
Schwertmann U (1964) Differenzierung der Eisenoxide des Bodens durch Extraktion mit Ammoniumoxalat-Lösung. Z Pflanzenernähr Düng Bodenk 105: 194–202
Schwertmann U (1988) Some properties of soil and synthetic iron oxides. In: Stucki JW, Goodman BA and Schwertmann U (eds.) Iron in Soils and Clay Minerals (NATO Advanced Inst), pp. 203–250. Bad Windsheim, W. Germany: Reidel Publishing Co.
Schwertmann U and Taylor RM (1989) Iron oxides. In: Dixon JB and Weed SR (eds.) Minerals in Soil Environments, 2nd edn., pp. 379–438. Madison, Wisc.: Soil Science Society of America
Sibbesen E (1978) An investigation of the anionexchange resin method for soil phosphate extraction. Plant Soil 50: 305–321
Singer A (1978) Phosphorus retention in some basalt and tuff derived Mediterranean soils. Agrochimica 22: 75–82
Solís P and Torrent J (1989a) Phosphate sorption by calcareous Vertisols and Inceptisols of Spain. Soil Sci Soc Am J 53: 456–459
Solís P and Torrent J (1989b) Phosphate fractions in calcareous Vertisols and Inceptisols of Spain. Soil Sci Soc Am J 53: 462–466
Toreu BN, Thomas FG and Gillman JP (1988) Phosphate-sorption characteristics of soils of the North Queensland coastal region. Aust J Soil Res 26: 465–477
White RE (1981) Retention and release of phosphate by soils and soil constituents. In: Tinker PB (ed.) Soils and Agriculture; Critical Reports on Applied Chemistry, Vol 2. New York: Halstead Press
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Peña, F., Torrent, J. Predicting phosphate sorption in soils of mediterranean regions. Fertilizer Research 23, 173–179 (1990). https://doi.org/10.1007/BF01073433
Received:
Accepted:
Issue Date:
DOI: https://doi.org/10.1007/BF01073433