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Derivatization procedures for reducing oligosaccharides, part 2: Chemical transformation of 1-deoxy-1-(4-trifluoroacetamidophenyl)aminoalditols

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Abstract

Three chemical transformations of oligosaccharide 1-deoxy-1-(4-trifluoroacetamidophenyl)aminoalditols are described. 1) Oxidation with hydrogen peroxide to give the corresponding reducing oligosaccharides. 2) Oxidation with cerium ammonium nitrate to give the corresponding 1-amino-1-deoxyalditols. 3) Treatment with acetic anhydride to give the correspondingN-acetylated derivatives, which are more stable towards oxidation.

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Authors and Affiliations

  1. Department of Carbohydrate Chemistry, University of Lund, S-223 70, Lund, Sweden

    Elisabeth Kallin

  2. Organic Synthesis Department, BioCarb AB, S-223 70, Lund, Sweden

    Hans Lönn & Thomas Norberg

Authors
  1. Elisabeth Kallin
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  2. Hans Lönn
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  3. Thomas Norberg
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Kallin, E., Lönn, H. & Norberg, T. Derivatization procedures for reducing oligosaccharides, part 2: Chemical transformation of 1-deoxy-1-(4-trifluoroacetamidophenyl)aminoalditols. Glycoconjugate J 5, 145–150 (1988). https://doi.org/10.1007/BF01061203

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  • DOI: https://doi.org/10.1007/BF01061203

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