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Ring opening metathesis polymerization of 1,1-diphenyl-1-sila-cyclopent-3-ene

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Summary

1,1-Diphenyl-1-silacyclopent-3-ene (I) has been polymerized by ring opening metathesis using tungsten hexachloride and either cyclopentene or cyclohexene as an initiator, with or without tetraphenyltin as a cocatalyst. The product polymer poly(1,1-diphenyl-1-sila-cis-pent-3-ene) (II) has been characterized by1H,13C, and29Si NMR and IR spectroscopy.

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Authors and Affiliations

  1. D. P. and K. B. Loker Hydrocarbon Research Institute, Department of Chemistry, University of Southern California, 90089-1661, Los Angeles, CA, USA

    Derek A. Stonich & William P. Weber

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  1. Derek A. Stonich
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  2. William P. Weber
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Stonich, D.A., Weber, W.P. Ring opening metathesis polymerization of 1,1-diphenyl-1-sila-cyclopent-3-ene. Polymer Bulletin 25, 629–631 (1991). https://doi.org/10.1007/BF01032657

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