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Size dependence of self-diffusion in the hard-square lattice gas

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Abstract

A striking size dependence of the mean-square displacement of diffusing particles in the two-dimensional lattice gas of hard squares has been observed by Monte Carlo simulation. It is shown that the size effect is due to the formation of a stable cage structure in small lattices when the particle concentration is high. The formation of cages is governed by a new type of percolation problem related to bootstrap percolation.

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Jäckie, J., Froböse, K. & Knödler, D. Size dependence of self-diffusion in the hard-square lattice gas. J Stat Phys 63, 249–260 (1991). https://doi.org/10.1007/BF01026602

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  • DOI: https://doi.org/10.1007/BF01026602

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