Abstract
A mode-coupling formalism is developed for multicomponent systems of particles performing diffusive motion in a uniform host medium. The mode-coupling equations are derived from a set of nonlinear fluctuating diffusion equations by expanding the concentration-dependent diffusion constants about their equilibrium values. From the mode-coupling equations the dominant long time behavior of current-current and super-Burnett correlation functions is derived. As specific applications I consider the long time behaviors of these correlation functions for collective and tracer diffusion in a one-component lattice gas with particle-conserving stochastic dynamics. The results agree with those from exactly solvable models and computer simulations.
Similar content being viewed by others
References
L. P. Kadanoff and J. Swift,Phys. Rev. 165:310 (1968); K. Kawasaki,Ann. Phys. (N.Y.) 61:1 (1970).
M. H. Ernst, E. H. Hauge, and J. M. J. van Leeuwen,Phys. Rev. Lett. 25:1254 (1970); Y. Pomeau and P. Résibois,Phys. Rep. C 19:63 (1975).
M. H. Ernst, E. H. Hauge, and J. M. J. van Leeuwen,Phys. Rev. A 4:2055 (1971).
J. R. Dorfman and E. G. D. Cohen,Phys. Rev. Lett. 25:1257 (1970);Phys. Rev. A 6:776 (1972);Phys. Rev. A 12:292 (1975).
Y. Pomeau,Phys. Rev. A 3:1174 (1971); P. Résibois,Physica 70:413 (1970); M. Theodosopulu and P. Résibois,Physica A 82:47 (1976).
D. Bedeaux and P. Mazur,Physica 73:431 (1974);Physica 75:79 (1974).
D. Forster, D. Nelson, and M. J. Stephen,Phys. Rev. Lett. 36:867 (1976).
B. J. Alder and T. E. Wainwright,Phys. Rev. A 1:18 (1970); J. J. Erpenbeck and W. W. Wood,Phys. Rev. A 26:1648 (1982).
H. A. Lorentz,Proc. R. Acad. Amst. 7:438, 585, 684 (1905); E. H. Hauge, What can one learn from Lorentz models?, inTransport Phenomena, G. Kirczenow and J. Marro, eds., Lecture Notes in Physics, Vol. 31, p. 337 (Springer, Berlin, 1974).
M. H. Ernst and A. Weyland,Phys. Lett. A 34:39 (1971).
B. J. Alder and W. E. Alley, inPerspectives in Statistical Physics, Studies in Statistical Mechanics, Vol. IX, H. J. Raveché, ed. (North-Holland, Amsterdam, 1981).
M. H. Ernst, J. Machta, J. R. Dorfman, and H. van Beijeren,J. Stat. Phys., to appear.
K. Kawasaki,Phys. Rev. 145:224 (1966);Phys. Rev. 148:375 (1966);Phys. Rev. 150:285 (1966).
W. Dietrich, I. Peschel, and W. R. Schneider,Commun. Phys. 2:175 (1977); H. Singer and I. Peschel,Z. Phys. B 39:333 (1980).
W. Zwerger,Z. Phys. B 42:333 (1981); S. Katz, J. L. Lebowitz, and H. Spohn,J. Stat.Phys., to appear.
E. J. Harris,Transport and Accumulation in Biological Systems (Butterworths Scientific Publications, London, 1960); E. J. A. Lea,J. Theor. Biol. 5:102 (1963); H. Rickert,Z. Phys. Chem. Neue Folge 43:129 (1964).
S. Alexander and P. Pincus,Phys. Rev. B 18:2011 (1978).
H. van Beijeren, K. W. Kehr, and R. Kutner,Phys. Rev. B 28:5711 (1983).
K. W. Kehr, unpublished.
H. van Beijeren and K. W. Kehr, to be published.
R. Kutner, to be published.
S. Ma,Modern Theory of Critical Phenomena (Benjamin, London, 1976).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
van Beijeren, H. Mode-coupling theory for purely diffusive systems. J Stat Phys 35, 399–412 (1984). https://doi.org/10.1007/BF01014393
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF01014393