Abstract
(E)-β-Farnesene, the major component of the alarm pheromone of many aphids, is prepared in 65% yield by passing commercial nerolidol through an evacuated column of alumina, treated with pyridine, at 200° C. The product is stored without air and applied to aphids as vapor at low speed (ca. 230 mm/sec) in air or nitrogen. The response of eight economically important aphid species was assessed in the laboratory; over 90% ofMyzus persicae responded in a large scale trial.
Similar content being viewed by others
References
Anet, E.F.L.J. 1970. Synthesis of (E,Z)-α-, (Z,Z)-α-and (Z)-β-farnesene.Aust. J. Chem. 23:2101–1208.
Bhati, A. 1963. Transformations by strong alkali.Perfum. Essent. Oil Rec. 54:376–381.
Bowers, W.S., Nault, L.R., Webb, R.E., andDutky, S.R. 1972. Aphid alarm pheromone: Isolation, identification, synthesis.Science 177:1121–1122.
Dawson, G.W.,Gibson, R.W.,Griffith, D.C.,Pickett, J.A.,Rice, A.D., andWoodcock, C.M. 1982. Aphid alarm pheremone derivatives affecting seltling and the transmission of plant viruses.J. Chem. Ecol. (in press).
Edwards, L.J., Siddall, J.B., Dunham, L.L., Uden, P., andKislow, C.J. 1973. Trans-β-farnesene alarm pheromone of the green peach aphid,Myzus persicae Sulzer.Nature 241:126–127.
Griffiths, D.C., andPickett, J.A. 1980. A potential application of aphid alarm pheromones.Entomol. Exp. Appl. 27:199–201.
Pickett, J.A., andGriffiths, D.C. 1980. Composition of aphid alarm pheromones.J. Chem. Ecol. 6:349–360.
Von Rudloff, E. 1961. A simple reagent for the specific dehydration of terpene alcohols.Can. J. Chem. 39:1860–1864.
Wientjens, W.H.J.M., Lakwijk, A.C. andVan Der Marel, T. 1973. Alarm pheromone of grain aphids,Experentia 29:658–660.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Dawson, G.W., Griffiths, D.C., Pickett, J.A. et al. Improved preparation of (E)-β-farnesene and its activity with economically important aphids. J Chem Ecol 8, 1111–1117 (1982). https://doi.org/10.1007/BF00986981
Received:
Revised:
Issue Date:
DOI: https://doi.org/10.1007/BF00986981