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ViscosityB-coefficients, structural entropies and heat capacities, and the effects of ions on the structure of water

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Abstract

The water-structural contributions to the entropies and heat capacities of hydration of over 120 ions and the viscosity B-coefficients of nearly 80 aqueous ions are tabulated and correlated. B-coefficients for many more ions are predicted from this relationship and from their dependence on ionic size and charge. The structural entropies determine a unique scale of water structure making and breaking by the ions.

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References

  1. Y. Marcus,J. Chem. Soc., Faraday Trans. I 82, 233 (1986).

    Google Scholar 

  2. M. H. Abraham and Y. Marcus,J. Chem. Soc., Faraday Trans. I 82, 3255 (1986).

    Google Scholar 

  3. Y. Marcus,J. Chem. Soc., Faraday Trans. I 83, 339 (1987).

    Google Scholar 

  4. Y. Marcus,Pure Appl. Chem 59, 1093 (1987).

    Google Scholar 

  5. Y. Marcus,J. Chem. Soc., Faraday Trans. 87, 2995 (1991).

    Google Scholar 

  6. Y. Marcus,J. Chem. Soc., Faraday Trans. 89, 713 (1993).

    Google Scholar 

  7. Y. Marcus,Biophys. Chem., in press, 1994.

  8. Y. Marcus, unpublished results;cf. Ion Solvation, (Wiley, Chichester, 1985), pp. 125–127.

  9. Y. Marcus and A. Ben-Naim,J. Chem. Phys. 83, 4744 (1985).

    Google Scholar 

  10. B.E. Conway,J. Solution Chem. 7, 721 (1978).

    Google Scholar 

  11. A. Ben-Naim and Y. Marcus,J. Chem. Phys. 81, 2016 (1984).

    Google Scholar 

  12. R. W. Gurney,Ionic Process in Solution, (McGraw-Hill, New York, 1953), p. 173.

    Google Scholar 

  13. D. T. Burns,Electrochim. Acta 10, 985 (1965).

    Google Scholar 

  14. G. A. Krestov,Zh. Strukt. Khim. 3, 137 (1962);Thermodynamics of Solvation, (Prentice Hall, New York, 1991).

    Google Scholar 

  15. J. E. Desnoyers and G. Perron,J. Solution Chem. 1, 199 (1972).

    Google Scholar 

  16. V. K. Abrozimov,Radiokhimiya 14, 916 (1972); H. L. Friedman and C. V. Krishnan, inWater: A Comprehensive Treatise, F. Franks, ed., (Plenum Press, New York, 1973), Vol. 3.

    Google Scholar 

  17. R. A. Robinson and R. H. Stokes,Elecrolyte Solutions, 2nd edn., Butterworths, London, 1954), p. 465.

    Google Scholar 

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Authors and Affiliations

  1. Department of Inorganic and Analytical Chemistry, The Hebrew University of Jerusalem, 91904, Jerusalem, Israel

    Y. Marcus

  2. School of Mathematical and Physical Sciences, Murdoch University, 6150, Murdoch, WA, Australia

    Y. Marcus

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  1. Y. Marcus
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Marcus, Y. ViscosityB-coefficients, structural entropies and heat capacities, and the effects of ions on the structure of water. J Solution Chem 23, 831–848 (1994). https://doi.org/10.1007/BF00972677

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  • DOI: https://doi.org/10.1007/BF00972677

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