Abstract
Synthetic zeolites may be used as catalysts for the condensation of acetals and ketals with vinyl ethers, leading to 1,1,3-trialkoxyalkanes. The Nd forms of dealuminized Y zeolites were found to be most efficient in this reaction.
Literature cited
L. A. Yanovskaya, S. S. Yufit, and V. F. Kucherov, The Chemistry of Acetals [in Russian], Nauka, Moscow (1975).
S. M. Makin, Pure Appl. Chem.,47, 173 (1976).
U. Brüggen, R. Lammers, and H. Mayr, J. Org. Chem.,53, 2920 (1988).
D. Fishman, J. T. Klug, and A. Shani, Synthesis, 137 (1981).
F. Effenberger, Angew. Chem.,81, 374 (1969).
S. M. Makin, S. M. Gabrielyan, A. S. Chebotarev, et al., Zh. Org. Khim.,10, 2044 (1974).
I. N. Nazarov, S. M. Makin, and B. K. Kruptsov, Dokl. Akad. Nauk SSSR,117, 823 (1957).
G. I. Samokhvalov, L. A. Vakulova, T. V. Men, et al., Zh. Obshch. Khim.,29, 2575 (1959).
G. T. Kerr, J. Phys. Chem.,72, 2529 (1968).
Ya. I. Isakov and Kh. M. Minachev, Usp. Khim.,51, 2069 (1982).
K. V. Topchieva and Ho Shi Thoang, The Activity and Physicochemical Properties of High-Silica Zeolites in Zeolite Catalysts [in Russian], Izd. Mosk. Gos. Univ., Moscow (1976).
Kh. M. Minachev and Ya. I. Isakov, The Preparation, Activation, and Regeneration of Zeolite Catalysts [in Russian], TsNIITÉneftekhim, Moscow (1971).
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 902–905, April, 1990.
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Cheskis, B.A., Isakov, Y.I., Novikov, A.V. et al. Zeolites as catalysts for the condensation of acetals with vinyl ethers. Russ Chem Bull 39, 809–811 (1990). https://doi.org/10.1007/BF00960352
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DOI: https://doi.org/10.1007/BF00960352