Conclusions
A dependence was found for the isomer composition of the quinolide peroxides formed upon the oxidation of 2,4,6-tri-tert-butylphenol on the coordination capacity of the metal compounds used for the oxidation and the medium. Kinetic measurements showed that the reaction of 2,4,6-tri-tert-butylphenoxyl with oxygen is accelerated in the presence of manganese diacetate.
Literature cited
C. D. Cook and R. Woodworth, J. Am. Chem. Soc.,75, 6242 (1953).
V. A. Roginskii, L. G. Plekhanova, V. Z. Dubinskii, G. A. Nikiforov, V. B. Muller, and V. V. Ershov, Izv. Akad. Nauk SSSR, Ser. Khim., 1327 (1975).
E. Muller and K. Ley, Chem. Ber.,87, 922 (1954).
B. P. Nikol'skii (editor), Chemist's Handbook [in Russian], 2nd ed., Vol. 3, Khimiya, Moscow-Leningrad (1964), p. 323.
A. Balaban, Rev. Roum. Chim.,14, 1281 (1969).
C. D. Cook, D. A. Kuhn, and P. Fiany, J. Am. Chem. Soc.,78, 2002 (1956).
Author information
Authors and Affiliations
Additional information
Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 3, pp. 706–709, March, 1986.
Rights and permissions
About this article
Cite this article
Vol'eva, V.B., Ivanov, E.V., Batanov, I.A. et al. Reaction of 2,4,6-tri-tert-butylphenoxyl with oxygen in the presence of metal compounds. Russ Chem Bull 35, 648–650 (1986). https://doi.org/10.1007/BF00953251
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF00953251