Skip to main content
SpringerLink
Log in

Photochromic and thermochromic spirans

VII. Spiro(4-oxo-3,4-dihydro-2H-1,3-benzoxazin-2,2′-[2H]benzophyrans)

  • Published:
Chemistry of Heterocyclic Compounds Aims and scope

Abstract

New spiropyrans of the 4-oxo-3,4-dihydro-2H-1,3-benzoxazine series, individual representatives of which have photochromic properties, were obtained by condensation of 2-alkyl-4-oxo-1,3-benzoxazinium perchlorates with aromatic o-hydroxy aldehydes in acetic acid and subsequent treatment of the 2-(o-hydroxystyryl) derivatives with pyridine or triethylamine. The structures of the synthesized compounds were confirmed by the PMR, IR, and UV spectroscopic data.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

Literature cited

  1. V. I. Minkin, L. E. Nivorozhkin, N. S. Trofimova, Yu. V. Revinskii, M. I. Knyazhanskii, and N. V. Volbushko, Zh. Org. Khim.,11, 828 (1975).

    Google Scholar 

  2. Yu. I. Ryabukhin, V. V. Mezheritskii, and G. N. Dorofeenko, Khim. Geterotsikl. Soedin., No. 4, 460 (1975).

    Google Scholar 

  3. Yu. I. Ryabukhin, V. V. Mezheritskii, V. D. Karpenko, and G. N. Dorofeenko, Khim. Geterotsikl. Soedin., No. 9, 1184 (1975).

    Google Scholar 

  4. G. Beisenherz, G. Ohnacker, A. Ackermann, and A. Kaiser, Arzneim.-Forsch.,7, 653 (1967).

    Google Scholar 

  5. S. E. Dowmon and G. B. Sutherland, Nature,164, 440 (1949).

    Google Scholar 

  6. É. R. Zakhs, E. V. Bashut-skaya, and L. S. Éfros, Khim. Geterotsikl. Soedin., No. 6, 818 (1976).

    Google Scholar 

  7. B. Ya. Simkin, V. I. Minkin, and L. E. Nivorozhkin, Khim. Geterotsikl. Soedin. (1978), in press).

  8. Laboratoires Robert & Carriere, French Patent No. 1096209 (1955); Chem. Abstr.,53, 4219h (1959).

    Google Scholar 

  9. B. Grudsinski, Acta Chim.,8, 105 (1962); Chem. Abstr.,59, 7476a (1963).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Scientific-Research Institute of Physical and Organic Chemistry, Rostov State University, 344006, Rostov-On-Don

    B. S. Luk'yanov, Yu. I. Ryabukhin, G. N. Dorofeenko, L. E. Nivorozhkin & V. I. Minkin

Authors
  1. B. S. Luk'yanov
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Yu. I. Ryabukhin
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. G. N. Dorofeenko
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. L. E. Nivorozhkin
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. V. I. Minkin
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

See [1] for communication VI.

Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 2, pp. 161–166, February, 1978.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Luk'yanov, B.S., Ryabukhin, Y.I., Dorofeenko, G.N. et al. Photochromic and thermochromic spirans. Chem Heterocycl Compd 14, 122–127 (1978). https://doi.org/10.1007/BF00945321

Download citation

  • Received:

  • Revised:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00945321

Keywords

Search

Navigation