Conclusions
Norbornene is dimerized in the presence of a nickel-containing catalytic system to give exo-2-(4′-methylenecyclohex-1′-en-3′-yl)norbornane in 67% yield.
Literature cited
P. Heimbach, R. V. Meyer, and G. Wilke, Ann. Chem.,2, 743 (1975).
H. Sato and T. Inukai, Bull. Chem. Soc. Jpn.,45, 944 (1970).
U. S. Patent 3,692,854; Chem. Abstr.,77, 139468 (1972).
D. T. Laverty, M. Anthony, M. Kervey, J. J. Rooney, and A. Stewart, J. Chem. Soc. Chem. Commun., 1976, No. 6, 193.
G. C. Levy and G. L. Nelson, Carbon-13 Nuclear Magnetic Resonance for Organic Chemists, Wiley (1972).
A. Weissberger (editor), Establishing the Structures of Organic Compounds by Physical and Chemical Methods [Russian translation], Vol. 1, Khimiya (1967), p. 95.
E. J. Agnello and G. D. Laubach, J. Am. Chem. Soc.,82, 4293 (1960).
S. Yoshikawa, K. Aoki, J. Kiji, and J. Furukawa, Tetrahedron,30, 405 (1974).
U. M. Dzhemilev, A. G. Kukovinets, and G. A. Tolstikov, Izv. Akad. Nauk SSSR, Ser. Khim.,1978, 1379.
Author information
Authors and Affiliations
Additional information
Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 910–913, April, 1979.
Rights and permissions
About this article
Cite this article
Dzhemilev, U.M., Khusnutdinov, R.I., Galeev, D.K. et al. Homodimerization of bicyclo[2.2.1]-2-heptene in presence of complex nickel catalysts. Russ Chem Bull 28, 854–856 (1979). https://doi.org/10.1007/BF00923600
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF00923600