Conclusions
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1.
α-Ketophosphonic acids are synthesized by hydrogenation of their benzyl esters.
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2.
The possibility of nonenzymatic transamination of α-ketophosphonic acids without rupure of the C-P bond is shown.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 6, pp.1391–1394, June, 1978.
The authors wish to thank A. T. Prudchenko for interpretation of the PMR spectra and I. A. Gandurina for plotting the TR spectra.
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Khomutov, R.M., Osipova, T.I. & Zhukov, Y.N. Synthesis of α-ketophosphonic acids. Russ Chem Bull 27, 1210–1213 (1978). https://doi.org/10.1007/BF00923378
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DOI: https://doi.org/10.1007/BF00923378