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Cationic polymerization of 1-vinyl-2,2,3,3-tetrafluorocyclobutane oxide

  • Organic and Biological Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The polymerization of 1-vinyl-2,2,3,3-tetrafluorocyclobutane oxide in the presence of cationic catalysts (BF3 etherates, FeCl3, Al2(SO4)3·3H2SO4·7H2O, SnCl4, or Al(C2H5)3+H2O) has been studied for the first time; high molecular weight polymers can be prepared when Al2(SO4)3·3H2SO4·7H2O, SnCl4, or Al(C2H5)3 +H2O is used.

  2. 2.

    The high molecular polymers of 1-vinyl-2, 2, 3,3-tetrafluorocyclobutane oxide prepared under the consitions indicated are amorphous and rubber-like materials with relatively high thermooxidative stability.

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry of the Academy of Sciences of the USSR, USSR

    V. A. Ponomarenko & N. M. Khomutova

Authors
  1. V. A. Ponomarenko
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  2. N. M. Khomutova
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 5, pp. 1153–1157, May, 1969.

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Ponomarenko, V.A., Khomutova, N.M. Cationic polymerization of 1-vinyl-2,2,3,3-tetrafluorocyclobutane oxide. Russ Chem Bull 18, 1054–1057 (1969). https://doi.org/10.1007/BF00922870

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  • DOI: https://doi.org/10.1007/BF00922870

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