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Mechanism of the reaction of hydrogen peroxide with oxopiperidine salts and piperidinoxyl radicals

  • Physical Chemistry
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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    Study has been made of the stoichiometry and kinetics of the oxidation of hydrogen peroxide by salts of 2,2,6,6-tetramethyl-1-oxopiperidine and 2,2,6,6-tetramethylpiperidin-1-oxyl. Piperidinoxyl, the primary product resulting from reduction of the oxopiperidine cation, is formed through electron transfer from HO −2 to\(\begin{array}{*{20}c} \setminus \\ / \\ \end{array} \mathop N\limits^ + = O\). The oxidizing action of the nitroxyl radical results from its acid disproportionation into\(\begin{array}{*{20}c} \setminus \\ / \\ \end{array} \mathop N\limits^ + = O\) and\(\begin{array}{*{20}c} \setminus \\ / \\ \end{array} N---OH\).

  2. 2.

    Rate constants have been determined for the reaction of HO −2 and HO .2 with\(\begin{array}{*{20}c} \setminus \\ / \\ \end{array} \mathop N\limits^ + = O\).

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Authors and Affiliations

  1. Chernogolovka Branch of the Institute of Chemical Physics, Academy of Sciences of the USSR, USSR

    V. D. Sen', V. A. Golubev, I. V. Kulyk & É. G. Rozantsev

Authors
  1. V. D. Sen'
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  2. V. A. Golubev
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  3. I. V. Kulyk
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  4. É. G. Rozantsev
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 8, pp. 1745–1754, August, 1976.

The authors wish to thank A. L. Aleksandrov for valuable comments in the course of a discussion of the results obtained in this work.

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Sen', V.D., Golubev, V.A., Kulyk, I.V. et al. Mechanism of the reaction of hydrogen peroxide with oxopiperidine salts and piperidinoxyl radicals. Russ Chem Bull 25, 1647–1654 (1976). https://doi.org/10.1007/BF00921418

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  • DOI: https://doi.org/10.1007/BF00921418

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