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Generation of free radicals in solutions and their reactions in model systems

  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Summary

  1. 1.

    The main types of oxidation-reduction systems for the initiation of free-radical processes in aqueous and hydrocarbon media are examined. The systems are classified according to the mechanisms by which they act.

  2. 2.

    An examination is made of the reactions of free alkyls and heteroradicals with various monomers and polymers occurring with rupture of C-H, C=C, C-C, and S-S bonds.

  3. 3.

    The part played by the “cage effect” in determining the thermostability of polymers is examined.

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Authors and Affiliations

  1. Institute of Macromolecular Compounds of the Academy of Sciences of the USSR, USSR

    B. A. Dolgoplosk, B. L. Erusalimskii & E. I. Tiniakova

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  1. B. A. Dolgoplosk
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  2. B. L. Erusalimskii
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  3. E. I. Tiniakova
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Dolgoplosk, B.A., Erusalimskii, B.L. & Tiniakova, E.I. Generation of free radicals in solutions and their reactions in model systems. Russ Chem Bull 7, 447–458 (1958). https://doi.org/10.1007/BF00910933

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  • DOI: https://doi.org/10.1007/BF00910933

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