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Untersuchungen der Fluoro-metallate(III), 2. Mitt.: Thermoanalytische Untersuchungen von Hydrazinium-(1+ und2+)-fluoro-aluminaten-gallaten, und-indaten

Fluoro metallates(III), II: Thermoanalytical investigation of hydrazinium(1+ and2+)-fluoroaluminates,-gallates, and-indates

  • Anorganische, Struktur- und Physikalische Chemie
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Monatshefte für Chemie / Chemical Monthly Aims and scope Submit manuscript

Zusammenfassung

Die thermische Zersetzung dieser Verbindungen im Argon wird beschrieben und führt zu den drei neuen Verbindungen N2H5GaF4, N2H5InF4 und N2H5GaF4·N2H6F2. Außerdem sind zwei neue Phasen mit den Verhältnissen N2H4∶2 Ga∶6 F und N2H4∶In∶3F isolierbar. Die thermische Zersetzung von N2H6AlF5 verläuft analog dem N2H6GaF5 ohne trennbare Stufen. Gitterabstände und IR-Spektren der neuisolierten Phasen sind angegeben.

Abstract

The thermal decomposition of these compounds in argon results in the following three new compounds: N2H5GaF4, N2H5InF4, and N2H5GaF4·N2H6F2. Besides, two new phases with composition N2H4∶2 Ga∶6 F and N2H4∶In∶3 F are noticed. The thermal decomposition of N2H6AlF5 follows the same path as N2H6GaF5, but no separable steps could be observed. IR spectra together with the d spacings of the new compounds are included.

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Authors and Affiliations

  1. Laboratorium für anorganische Chemie der Universität Ljubljana, Ljubljana, Slovenia

    Peter Bukovec & Jože Šiftar

  2. Institut “Jožef Stefan”, Ljubljana, Slovenia

    Peter Bukovec & Jože Šiftar

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  1. Peter Bukovec
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  2. Jože Šiftar
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Bukovec, P., Šiftar, J. Untersuchungen der Fluoro-metallate(III), 2. Mitt.: Thermoanalytische Untersuchungen von Hydrazinium-(1+ und2+)-fluoro-aluminaten-gallaten, und-indaten. Monatshefte für Chemie 102, 94–101 (1971). https://doi.org/10.1007/BF00909213

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  • DOI: https://doi.org/10.1007/BF00909213

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