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Untersuchungen der Fluoro-metallate(III), 1. Mitt.: Hydrazinium(1+ und2+)-fluoro-aluminate,-gallate und-indate

Fluoro metallates (III), I.: Hydrazinium(1+ and2+)-fluoroaluminates,-gallates, and-indates

  • Anorganische, Struktur- und Physikalische Chemie
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Monatshefte für Chemie / Chemical Monthly Aims and scope Submit manuscript

Zusammenfassung

Vier neue Hydraziniumfluorometallate des Galliums und zwei neue des Indiums sowie das schon bekannte Pentafluoroaluminat wurden erhalten. Bei deren Herstellung spielt die Konzentration des Hydrogenfluorids eine ausschlaggebende Rolle. Auf Grund IR-spektroskopischer Daten ist eine oktaedrische Koordination der Metall(III)-Ionen, in einigen Fällen unter Verknüpfung zu Ketten, am wahrscheinlichsten.

Abstract

Four new gallium and two new indium compouds are described besides the already known hydrazinium(2+)-pentafluoraluminate. The concentration of hydrogen fluoride is shown to be of primary importance in their preparation. On the basis of IR spectra octahedral coordination of Me(III) ions seems to be most probable, in few cases these octahedra are joined through corners in chains.

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Authors and Affiliations

  1. Laboratorium für anorganische Chemie der Universität Ljubljana und Institut „Jožef Stefan”, Ljubljana

    Jože Šiftar & Peter Bukovec

Authors
  1. Jože Šiftar
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  2. Peter Bukovec
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Additional information

Teil eines Referates auf dem II. Europäischen Fluor-Symposium in Göttingen, August 1968.

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Šiftar, J., Bukovec, P. Untersuchungen der Fluoro-metallate(III), 1. Mitt.: Hydrazinium(1+ und2+)-fluoro-aluminate,-gallate und-indate. Monatshefte für Chemie 101, 1184–1188 (1970). https://doi.org/10.1007/BF00908564

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  • DOI: https://doi.org/10.1007/BF00908564

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