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Die Kristallstruktur der Verbindung Li2ZnGeO4

The crystal structure of the compoundLi 2 ZnGeO 4

  • Anorganische, Struktur- und Physikalische Chemie
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Monatshefte für Chemie / Chemical Monthly Aims and scope Submit manuscript

Abstract

The crystal structure of dilithiumzine orthogermanate, Li2ZnGeO4, has been determined and refined byFourier syntheses and least-squares, using three dimensional single-crystal data. A finalR-value of 5.7% was obtained. The monoclinic unit cell (Pn−Cs 2) with the dimensionsa=6.40,b=5.45,c=5.04 Å and β=90.2° contains two formula units Li2ZnGeO4. The crystal structure is built up by [GeO4] tetrahedra, which are linked together by [LiO4] and [ZnO4] tetrahedra. The average interatomic distances are found to be: Ge−O=1.77, Li−O=2.01 and Zn−O=1.93 Å.

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Literatur

  1. H. Völlenkle undA. Wittmann, Z. Kristallogr.128, 66 (1969).

    Google Scholar 

  2. W. Schütz, Z. physik. Chem.31 B, 292 (1936).

    Google Scholar 

  3. E. Plattner, Diplomarbeit, Technische Hochschule Wien, 1971.

  4. E. Plattner, Dissertation, Technische Hochschule Wien, 1974.

  5. J. Zemann, Acta cryst. [Kopenhagen]13, 863 (1960).

    Google Scholar 

  6. Ch. Keffer, A. Mighell, F. Mauer, H. Swanson undS. Block, Inorg. Chem.6, 119 (1967).

    Google Scholar 

  7. A. R. West undF. P. Glasser, J. Mater. Sci.5, 557 (1970).

    Google Scholar 

  8. Chang, Han-Ching, Acta geol. sinica46, 76 (1966); Chem. Abstr.65, 11457 h (1976).

    Google Scholar 

  9. W. H. Zachariasen undW. L. Bragg, Z. Kristallogr.72, 518 (1930).

    Google Scholar 

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Authors and Affiliations

  1. Institut für Mineralogie, Kristallographie und Strukturchemie, Technische Universität Wien, Getreidemarkt 9, A-1060, Wien, Österreich

    Edmund Plattner, Horst Völlenke & Alfred Wittmann

Authors
  1. Edmund Plattner
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  2. Horst Völlenke
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  3. Alfred Wittmann
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Plattner, E., Völlenke, H. & Wittmann, A. Die Kristallstruktur der Verbindung Li2ZnGeO4 . Monatshefte für Chemie 107, 921–927 (1976). https://doi.org/10.1007/BF00904478

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  • DOI: https://doi.org/10.1007/BF00904478

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