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Measurement of total dissolved phosphorus in small volumes of iron rich interstitial water

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Abstract

It is shown that sorption of orthophosphate to iron compounds, formed during persulfate digestion, can cause a significant underestimation of total dissolved phosphorus in interstitial waters rich in iron and poor in phosphorus. Labelling the samples with carrier free32PO4 before digestion allows to correct for these losses.

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References

  • Belzile, N. and A. Tessier, 1990. Interactions between arsenic and iron oxyhydroxides in lacustrine sediments. Geochim. Cosmochim. Acta. 54:103–109.

    Google Scholar 

  • Boers, P. C. M., O. van Hese, F. de Bles, and Th. E. Cappenberg, 1985. The release of dissolved organic phosphorus from the peaty sediments of the shallow eutrophic Loosdrecht Lakes (The Netherlands). 3rd Internat. Symposium. Interactions Between Sediments and Waters. Geneva — August 1984.

  • Carignan, R., 1988. Seasonal dynamics of sulfate and hydrogen sulfide near the sediment-water interface of an oligotrophic acid lake. Verh. Internat. Verein. Limnol., 23:106–115.

    Google Scholar 

  • Carignan, R. and J. O. Nriagu, 1985. Trace metal deposition and mobility in the sediments of two lakes near Sudbury, Ontario. Geochim. Cosmochim. Acta. 49:1753–1764.

    Google Scholar 

  • Carignan, R. and D. R. S. Lean, 1991. Regeneration of dissolved substances in a seasonally anoxic lake: The relative importance of processes occuring in the water column and in the sediments. Limnol. Oceanogr. (in press).

  • Chapman, B. M., D. R. Jones, and R. F. Jung, 1983. Processes controlling metal ion attenuation in acid mine drainage streams. Geochim. Cosmochim. Acta, 47:1957–1973.

    Google Scholar 

  • Enell, M. and S. Löfgren, 1987. Phosphorus in Interstitial water: Methods and dynamics. Hydrobiologia, 170:103–132.

    Google Scholar 

  • Hesslein, R. H., 1976. Anin situ sampler for close interval pore water studies. Limnol. Oceanogr. 21:912–914.

    Google Scholar 

  • Holdren, G. C. Jr and D. E. Armstrong, 1980. Factors affecting phosphorus release from intact lake sediment cores. Environ. Sci. Technol., 14:79–87.

    Google Scholar 

  • Holdren, G. R. Jr. and O. P. Bricker, 1977. Distribution and Control of dissolved iron and manganese in the interstitial waters of the Chesapeake Bay. Biological Implications of Metals in the Environment. Proc. of the 15th. Ann. Hanford Life Symp. 1975. Conf. 750929, ERDA Symp. Ser. 178–196.

  • Löfgren, S., 1987. P retention in sediments. Implications for aerobic phosphorus release in shallow lakes. PhD dissertation Uppsala University. ISBN 91-554-2079-6.

  • Nembrini, G., J. A. Capobianco, J. Garcia, and J.-M. Jacquet, 1982. Interaction between interstitial water and sediment in two cores of Lac Léman. Switzerland. Hydrobiologia. 92:363–375.

    Google Scholar 

  • Ostrofsky, M. L., D. A. Osborne, and T. J. Zebulske, 1989. Relationship between anaerobic phosphorus release rates and sedimentary phosphorus species. Can. J. Fish. Aquat. Sci. 46:416–419.

    Google Scholar 

  • Peterson, M. L. and R. Carpenter, 1986. Arsenic distributions in pore waters and sediments of Puget Sound, Lake Washington coast and Saanich Inlet, B.C. Geochim. Cosmochim. Acta. 50:353–369.

    Google Scholar 

  • Sakata, M., 1985. Diagenetic remobilization of manganese, iron, copper and lead in anoxic sediment of a fresh water pond. Water. Res. 19:1033–1038.

    Google Scholar 

  • Sondergaard, M., 1989. Phosphorus release from hypertrophic lake sediment: Experiments with intact sediment cores in a continuous flow system. Arch. Hydrobiol., 116:45–59.

    Google Scholar 

  • Stauffer, R. and D. E. Armstrong, 1986. Cycling of iron, manganese, phosphorus, calcium and potassium in two stratified bassins of Shaawa Lake., Minnesota. Geochim. Cosmochim. Acta, 50:215–229.

    Google Scholar 

  • Stumm, W. and J. J. Morgan, 1981. Aquatic chemistry. An Introduction Emphasizing Chemical Equilibria in Natural Waters. 2nd Edition. Wiley and Sons, New York, 780 p.

    Google Scholar 

  • Tessier, A., R. Carignan, B. Dubreuil, and F. Rapin, 1989. Partitioning of zinc between the water column and the oxic sediments in lakes. Geochim. Cosmochim. Acta. 53:1511–1522.

    Google Scholar 

  • Vogler, P., 1965. Fortschritte Wasserchem. u. Grenzgeb., 2:109–119.

    Google Scholar 

  • Wheeler, B. D. and K. E. Giller, 1984. The use of dialysis cells for investigating pore water composition in wetland substrata, with particular reference to dissolved iron and sulfide. Commun. in Soil Sci. Plant. Anal., 15:707–716.

    Google Scholar 

  • Weiler, R. R., 1973. The interstitial water composition in the sediments of the Great Lakes. I. Western Lake Ontario. Limnol. Oceanogr. 18:918–931.

    Google Scholar 

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Gächter, R., Tessier, A., Szabo, E. et al. Measurement of total dissolved phosphorus in small volumes of iron rich interstitial water. Aquatic Science 54, 1–9 (1992). https://doi.org/10.1007/BF00877261

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  • DOI: https://doi.org/10.1007/BF00877261

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