Abstract
A new bimetallic Pt-Sn compound [Pt(NH3)4][SnCl6] has been used as precursor for the preparation of supported Pt-Sn/Al2O3 catalysts. A comparison of a dried sample with that prepared by coimpregnation displays different behaviour in TPR, chemisorption. The initial catalytic activity properties were checked in the reactions of cyclohexane dehydrogenation and cyclopentane ring opening, whilen-hexane skeletal reactions were used to probe the quasisteady-state activity. The catalyst prepared via the Pt-Sn complex precursors exhibited some-what lower specific activity. This fact, together with enhanced olefin formation fromn-hexane was taken as an indication of lower amount of contiguous Pt atoms and some electronic interaction between Pt and Sn in that catalyst.
Similar content being viewed by others
References
R. Srinivasan and B.H. Davis, Platinum Metals Rev. 36 (1992) 151, and references therein.
R. Burch, J. Catal. 71 (1981) 348.
H. Lieske and J. Völter, J. Catal. 90 (1984) 96.
R. Burch and L.C. Garla, J. Catal. 71 (1981)360.
P. Biloen, J.N. Helle, H. Verbeek, F.M. Dautzenberg and W.M.H. Sachtler, J. Catal. 63 (1980) 112.
Y. Zhou and S.M. Davis, Catal. Lett. 15 (1992) 51.
J. Beltramini and D.L. Trimm, Appl. Catal. 31 (1987) 113.
B. Coq and F. Figueras, J. Catal. 85 (1984) 197.
R. Srinivasan and B.H. Davis, Appl. Catal. A 87 (1992) 45.
K. Balakrishnan and J. Schwank, J. Catal. 127 (1991) 287.
Y.X. Li, M. Stencel and B.H. Davis, Appl. Catal. 64 (1990) 71.
Y.J. Lei, Appl. Catal. 72 (1991) 33.
R. Srinivasan, L.A. Rice and B.H. Davis, J. Catal. 126 (1991) 257.
Y.X. Li and K.J. Klabunde, J. Catal. 126 (1990) 173.
B. Coq, A. Chaqroune, F. Figueras and B. Nciri, Appl. Catal. A 82 (1992) 231.
J.L. Margitfalvi, H.P. Jalett, E. Tálas, A. Baiker and H.U. Blaser, Catal. Lett 10 (1991) 325.
C. Vértes, E. Tálas, I. Czakó-Nagy, J. Ryczkowski, S. Göbölös, A. Vértes and J. Margitfalvi, Appl. Catal. 68 (1991) 149.
J.L. Margitfalvi, E. Tálas and S. Göbölös, Catal. Today 6 (1989) 73.
T.V. Kireeva, V.P. Doronin, L.Ya. Alt and V.K. Duplyakin, React. Kinet. Catal. Lett. 38 (1989) 7.
G.T. Baronetti, S.R. de Miguel, O.A. Scelza and A.A. Castro, Appl. Catal. 24 (1986) 109.
S.R. de Miguel, G.T. Baronetti, A.A. Castro and O.A. Scelza, Appl. Catal. 45 (1988) 61.
R.W. Joyner and E.S. Shpiro, Catal. Lett. 9 (1991) 239.
E. Garnier, A. El Mouahid and J. Cernak, Acta Cryst. C 50 (1994) 845.
M. Boudart, Adv. Catal. 20 (1969) 153.
Z. Paál, H. Groeneweg and H. Zimmer, Catal. Today 5 (1989) 199.
Z. Paál, Zh. Zhan, M. Räth and W. Gombler, J. Catal. 146 (1994) 342.
Z. Paál, Zh. Zhan, I. Manninger and M. Muhler, Appl. Catal. 66 (1990) 301.
A. El Biyyadh, M. Guérin, C. Kappenstein, D. Bazin and H. Dexpert, J. Chim. Phys. 86 (1989) 1751.
A.El Abed, M. Guérin and C. Kappenstein, unpublished.
F.G. Gault, Adv. Catal. 30 (1981) 1.
Z. Paál, Catal. Today 12 (1992) 297.
Z. Paál, M. Räth, B. Brose and W. Gombler, React. Kinet. Catal. Lett. 47 (1992) 43.
P. Biloen, F.M. Dautzenberg and W.M.H. Sachtler, J. Catal. 50 (1977) 77.
F.M. Dautzenberg, J.N. Helle and W.M.H. Sachtler, J. Catal. 63 (1980) 119.
A.A. Balandin, Adv. Catal. 19 (1969) 1.
J.R. Anderson, Adv. Catal. 23 (1973) 1.
Z. Paál, in:Hydrogen Effects in Catalysis, eds. Z. Paál and P.G. Menon (Dekker, New York, 1988) p. 449.
Z. Paál, H. Zimmer, J.R. Günter, R. Schlögl and M. Muhler, J. Catal. 119 (1989) 146.
Z. Paál, H. Groeneweg and J. Paál-Lukács, J. Chem. Soc. Faraday Trans. 86 (1990) 3159.
R. Burch, Catal. Today 10 (1991) 233.
Author information
Authors and Affiliations
Additional information
On leave from Fachhochschule Ostfriesland, D-26723 Emden, Germany.
Rights and permissions
About this article
Cite this article
Kappenstein, C., Saouabe, M., Guérin, M. et al. Characterization and activity of Pt-Sn/Al2O3 catalysts of different preparation: coimpregnation and new Pt-Sn precursor. Catal Lett 31, 9–17 (1995). https://doi.org/10.1007/BF00817028
Received:
Accepted:
Issue Date:
DOI: https://doi.org/10.1007/BF00817028