Conclusions
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1.
Diffusion of carbon inα andγ-irons is non-uniform: at 550 to 950°C, carbon enriches preferentially the grain boundaries; the diffusivity of carbon along grain boundaries of ferrite is three to four higher than inside the grain. An enrichment with carbon of theα-solid solution is also observed in regions adjoining the grain boundaries.
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2.
The diffusion rate and the distribution of carbon within a single grain are changed by alloying. Addition of substantial amounts of certain elements curtailing theγ loop considerably increases the penetration depth of carbon on account of boundary diffusion developing inγ-iron. The concentration gradient of carbon between boundary and interior of a grain is less in alloyed than in unalloyed iron.
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Bokshtein, S.Z., Gubareva, M.A., Kontorovich, I.E. et al. Peculiarities of the diffusion of carbon in iron. Met Sci Heat Treat 3, 6–9 (1961). https://doi.org/10.1007/BF00815232
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DOI: https://doi.org/10.1007/BF00815232