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Activity and stability of laser-photoreduced supported molybdenum oxide metathesis catalysts

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Abstract

Photoreduction of MoO3/SiO2 and MoO3/SiO2·Al2O3 catalysts in CO with a laser beam at 308 nm resulted, after addition of cyclopropane to form the active sites, in a high activity for alkene metathesis. Both catalyst systems are active for normal alkenes, e.g. propene, and for functionalized alkenes, e.g. methyl oleate, already at room temperature.

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Authors and Affiliations

  1. Department of Chemical Engineering, University of Amsterdam, Nieuwe Achtergracht 166, 1018, WV Amsterdam, The Netherlands

    J. C. Mol

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  1. J. C. Mol
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Mol, J.C. Activity and stability of laser-photoreduced supported molybdenum oxide metathesis catalysts. Catal Lett 23, 113–118 (1994). https://doi.org/10.1007/BF00812138

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  • DOI: https://doi.org/10.1007/BF00812138

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