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Organometallics derived (Pd + Ln)/SiO2 catalysts for the reactions of synthesis gas conversion

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Abstract

C3H6 hydroformylation and CH3OH synthesis on organometallics derived (Pd + Ln)/ SiO2 and Pd/SiO2 catalysts have been studied. The activity and selectivity towards methanol in CO + H2 reaction were observed to increase for all the modified catalysts while both the hydroformylation activity and selectivity towards oxygenates in C3H6 hydroformylation decreased for the catalysts in comparison to those of Pd/SiO2. The FTIR, TPD data and characteristic catalytic properties of the catalysts studied allow to suggest that C3H6 hydroformylation on (Pd + Ln)/SiO2 catalysts occurs on monometallic Pd clusters without participation of mixed active sites and CO complexes activated thereon.

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References

  1. Kh.M. Minachov, Yu.S. Khodakov, G.V. Antoshin and M.A. Markov,Rare Earths in Catalysis (Nauka, Moscow, 1972), in Russian.

    Google Scholar 

  2. N.S. Kozlov, G.M. Senkov, V.A. Polikarpov and V.V. Shipikin,The Catalysts of Reforming (Nauka i Tekhnika, Minsk, 1976), in Russian.

    Google Scholar 

  3. B.I. Kilbourn, J. Less-Common Metals 126 (1986) 101.

    Google Scholar 

  4. M.A. Vannice, J. Catal. 40 (1975) 123.

    Google Scholar 

  5. M.A. Vannice, S.-Y. Wang and S.H. Moon, J. Catal. 71 (1981) 152.

    Google Scholar 

  6. F. Fajula, R.G. Anthony and J.H. Lunsford, J. Catal. 73 (1982) 237.

    Google Scholar 

  7. R.F. Hicks and A.T. Bell, J. Catal. 90 (1984) 205.

    Google Scholar 

  8. H. Deligianni, R.L. Mieville and J.B. Peri, in:Proc. 8th Int. Congr. on Catalysis, Vol. 5, Berlin, 1984 (Verlag Chemie, Weinheim, 1984).

    Google Scholar 

  9. S. Ichikawa, H. Poppa and M. Boudart, J. Catal. 91 (1985) 1.

    Google Scholar 

  10. Yu.A. Ryndin, Yu.N. Nogin, V.I. Zaikovskii, K. Jakob, K.-H. Thiele and Yu.I. Yermakov, React. Kinet. Catal. Lett. 29 (1985) 395.

    Google Scholar 

  11. Yu.A. Ryndin, Yu.N. Nogin, Yu.V. Zverev, N.P. Chernyaev, F.G. Abdikova and Yu.I. Yermakov, React. Kinet. Catal. Lett. 31 (1986) 151.

    Google Scholar 

  12. J.S. Rieck and A.T. Bell, J. Catal. 99 (1986) 278.

    Google Scholar 

  13. J.S. Rieck and A.T. Bell, J. Catal. 103 (1987) 46.

    Google Scholar 

  14. Yu.N. Nogin, E.A. Paukshtis, A.V. Pashis and Yu.A. Ryndin, J. Mol. Catal. 55 (1989) 84.

    Google Scholar 

  15. A. Takeuchi and J.R. Katzer, J. Catal. 82 (1983) 351.

    Google Scholar 

  16. H. Orita, S. Naito and K. Tamaru, J. Chem. Soc. Chem. Commun. (1984) 150.

  17. M. Ichikawa and T.J. Fukushima, J. Chem. Soc. Chem. Commun. (1985) 321.

  18. F.R. Hartley,Supported Metal Complexes. A New Generation of Catalysts (Reidel, Dordrecht, 1985).

    Google Scholar 

  19. B.L. Moroz, V.A. Semikolenov, V.A. Likholobov and Yu. I. Yermakov, J. Chem. Soc. Chem. Commun. (1982) 1286.

  20. B.L. Moroz, I.L. Mudrakovskii, L.I. Bulgakova, V.A. Rogov, V.A. Likholobov, V.M. Mastikhin, L.A. Sazonov and Yu. I. Yermakov, in:Proc. 4th Int. Symp. on Heterogeneous Catalysis, Sofia 1987, Part2, p. 25.

  21. M. Kobayashi, Chem. Lett. (1984) 1215.

  22. A. Fukuoka, T. Kimura, N. Kosugi, H. Kuroda, Y. Minai, Y. Sakai, T. Tominaga and M. Ichikawa, J. Catal. 126 (1990) 434.

    Google Scholar 

  23. A. Maeda, F. Yamakawa, K. Kunimori and T. Uchijima, Catal. Lett. 4 (1990) 107.

    Google Scholar 

  24. W.R. Schoeller and A.R. Powell,The Analysis of Minerals and Ores of the Rare Earth Elements (Griffin, London, 1955).

    Google Scholar 

  25. Yu.I. Yermakov, B.N. Kuznetsov and V.A. Zakharov,Catalysis by Supported Complexes (Elsevier, Amsterdam, 1981).

    Google Scholar 

  26. T. Gonzalez, C.C. Jandula and F. Garcia, Z. Phys. Chem. NF 118 (1979) 99.

    Google Scholar 

  27. F. Meriaudeau, J.F. Dutel, M. Dufaux and C. Naccache, Stud. Surf. Sci. Catal. 11 (1982) 95.

    Google Scholar 

  28. J. Barrault, A. Alouche, F. Lenormand and G. Maire, in:Proc. 7th Colloq. Fr.-Sov. Catal., Strasbourg l986, p.48.

  29. J.S. Rieck and A.T. Bell, J. Catal. 96 (1985) 88.

    Google Scholar 

  30. C. Sudhakar and M.A. Vannice, Appl. Catal. 14 (1985) 47.

    Google Scholar 

  31. R.P. Eischens, W.A. Pliskin and S.A. Francis, J. Chem. Phys. 22 (1954) 1786.

    Google Scholar 

  32. Yu.I. Yermakov and B.N. Kuznetsov, Kinet. Catal. 18 (1977) 1167, in Russian.

    Google Scholar 

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Authors and Affiliations

  1. Institute of Catalysis, 5 Akademika Lavrentieva Street, 630090, Novosibirsk, Russia

    Yu. N. Nogin

  2. Institute of Chemistry of Natural Organic Materials, 42 K. Marx Street, 660049, Krasnoyarsk, Russia

    N. V. Chesnokov & V. I. Kovalchuk

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  1. Yu. N. Nogin
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  2. N. V. Chesnokov
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  3. V. I. Kovalchuk
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Nogin, Y.N., Chesnokov, N.V. & Kovalchuk, V.I. Organometallics derived (Pd + Ln)/SiO2 catalysts for the reactions of synthesis gas conversion. Catal Lett 23, 79–86 (1994). https://doi.org/10.1007/BF00812133

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  • DOI: https://doi.org/10.1007/BF00812133

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