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Konzentrationseffekte in Isocyanat-Alkohol-Systemen

Effects of concentrations in isocyanat-alcohol-systems

  • Anorganische Und Physikalische Chemie
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Monatshefte für Chemie / Chemical Monthly Aims and scope Submit manuscript

Summary

The reaction between aromatic isocyanate and alcohol in nonpolar solvents at different alcohol and isocyanate concentrations and the effect of the presence of urethane in this solution at the start of the reaction have been examined. The results indicate that the rate constants of the observed second-order equation are dependent on the concentration of the reactants and of the urethane.

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Literatur

  1. Baker J. W., Holdsworth J. B. (1947) J. Chem. Soc. (London): 713

  2. Baker J. W., Gaunt J. (1949) J. Chem. Soc. (London): 27

  3. Oberth A. E., Bruenner R. S. (1968) J. Phys. Chem.72: 845

    Google Scholar 

  4. Goroško S. A., Bakalo L. A., Lipatova T. E. (1975) Synthese, Phys. Chem. Polymere15: 3

    Google Scholar 

  5. Bondarenko S. P., Zaporožskaja S. V., Tiger R. P., Entelis S. G. (1986) Chem. Phys. (UdSSR)5: 1538

    Google Scholar 

  6. Ephraim S., Woodward A. E., Mesrobian R. B. (1958) J. Am. Chem. Soc.80: 1326

    Google Scholar 

  7. Pronina I. A., Spirin Ju. L., Blagonravova A. A., Arefeva S. M., Gantmacher A. R. (1966) Kinetik u. Katalyse (UdSSR)7: 439

    Google Scholar 

  8. Okada H., Iwakura Y. (1963) Makromol. Chem.66: 91

    Google Scholar 

  9. Thiele L., Wagner K., Appenroth S. (1988) Plaste u. Kautschuk35: 445

    Google Scholar 

  10. Thiele L. Monatsh. Chem.123: 865

  11. Fletcher A. N., Heller C. A. (1967) J. Phys. Chem.71: 3742

    Google Scholar 

  12. Thiele L., Frommelt H. (1979) Acta Polymerica30: 353

    Google Scholar 

  13. Thiele L., Becker R., Schimpfle H. U., Frommelt H. (1976) Plaste u. Kautschuk23: 558

    Google Scholar 

  14. Hauptmann R. (1984) Dissertation. Technische Universität Dresden

  15. Tiger R. P., Bechli L. S., Entelis S. G. (1971) Kinetik u. Katalyse (UdSSR)12: 318

    Google Scholar 

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Thiele, L. Konzentrationseffekte in Isocyanat-Alkohol-Systemen. Monatsh Chem 123, 875–882 (1992). https://doi.org/10.1007/BF00811542

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  • DOI: https://doi.org/10.1007/BF00811542

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