Skip to main content
SpringerLink
Log in

Low temperature FTIR spectroscopic study of ozone interaction with phenol adsorbed on silica and ceria

  • Published:
Catalysis Letters Aims and scope Submit manuscript

Abstract

The reactivity towards O3 of the different species formed from phenol adsorption on silica and ceria has been studied using IR spectroscopy by increasing the temperature from 77 K. It clearly appeared that on silica H-bonded phenol species were more reactive than phenoxy species, whereas on ceria monodentate phenoxy species were more active than bidentate species. Intermediate products of phenol oxidation were characterized by bands between 1800 and 1600 cm−1, that at 1750 cm−1 being probably due to the formation of a carboxylic acid.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. R.F. Christman and M.J. Ghassini, J. Am. Water Works Ass. 58 (1976) 773.

    Google Scholar 

  2. J.C. Evans, Spectrochim. Acta 16 (1960) 1382.

    Google Scholar 

  3. V.N. Abramov, A.V. Kiselev and V.I. Lygin, Russ. J. Phys. Chem. 38 (1964) 575.

    Google Scholar 

  4. M. Kubinyi, F. Billes, A. Grofcsik and G. Keresztury, J. Mol. Struct. 266 (1992) 339.

    Google Scholar 

  5. M.L. Konstantinova, S.D. Razumovskii and G.E. Zaikov, Izv. Akad. Nauk. SSSR, Ser. Khim. (1991) 320.

  6. X. Montagne, R. Boulet, E. Freund and J.C. Lavalley, Stud. Surf. Sci. Catal. 48 (1989) 695.

    Google Scholar 

  7. M.A. Babaeva, D.S. Bystrov, A.Y. Kovalgin and A.A. Tsyganenko, J. Catal. 123 (1990) 396.

    Google Scholar 

  8. K.M. Bulanin, A.V. Alekseev, D.S. Bystrov, J.C. Lavalley and A.A. Tsyganenko, J. Phys. Chem. 98 (1994) 5100.

    Google Scholar 

  9. C. Binet, A. Jadi and J.C. Lavalley, J. Chim. Phys. 89 (1992) 1441.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Laboratoire Catalyse et Spectrochimie, URA CNRS414, ISMRA-Université, 14050, Caen Cedex, France

    L. Mariey, J. Lamotte & J. C. Lavalley

  2. Institute of Physics, St. Petersburg University, 198904, St. Petersburg, Russia

    N. M. Tsyganenko & A. A. Tsyganenko

Authors
  1. L. Mariey
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. J. Lamotte
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. J. C. Lavalley
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. N. M. Tsyganenko
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. A. A. Tsyganenko
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Mariey, L., Lamotte, J., Lavalley, J.C. et al. Low temperature FTIR spectroscopic study of ozone interaction with phenol adsorbed on silica and ceria. Catal Lett 41, 209–211 (1996). https://doi.org/10.1007/BF00811493

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00811493

Keywords

Search

Navigation