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Thermodynamics and phase diagram of the gallium-sodium system

Thermodynamik und Phasendiagramm des Gallium-Natrium Systems

  • Anorganische Und Physikalische Chemie
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Monatshefte für Chemie / Chemical Monthly Aims and scope Submit manuscript

Abstract

A critical evaluation of the thermodynamic properties of liquid alloys was made. TheGibbs energies of formation of the solid compounds were derived from the original experimental data. Finally, calculations were carried out to match the thermodynamic description of the system to the known liquidus points.

Zusammenfassung

Es wurde eine kritische Auswertung der thermodynamischen Eigenschaften von flüssigen Legierungen durchgeführt. Von den experimentellen Daten wurden dieGibbs'schen Bildungsenergien der festen Verbindungen abgeleitet. Letztlich wurden Berechnungen zur Anpassung der thermodynamischen Beschreibung des Systems mit bekannten Liquidus-Punkten durchgeführt.

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References

  1. Zintl E, Kaiser H (1933) Z Anorg Chem 211: 121

    Google Scholar 

  2. Gilfillan ES, Bent HE (1934) J Am Chem Soc 56: 1661

    Google Scholar 

  3. Puschin NA, Stepanović S, Stajić V (1932) Z Anorg Chem 209: 333

    Google Scholar 

  4. Feschotte P, Rinck E (1956) Comp Rend 243: 1525

    Google Scholar 

  5. Feschotte P (1961) Ann Chim Paris 6: 1029

    Google Scholar 

  6. Rinck E, Feschotte P (1960) Comp Rend 250: 1489

    Google Scholar 

  7. Rinck E, Feschotte P (1960) Comp Rend 251: 869

    Google Scholar 

  8. Rinck E, Feschotte P (1961) Comp Rend 252: 3592

    Google Scholar 

  9. Yatsenko SP, Chuntonov KA, Bushmanov VD, Diyeva EN (1974) Diagrammy sostoyaniya sistem Ga-Na, Ga-K, In-K, In-Rb. In:Ivanov OS, Alekseeva ZM (eds) Struktura faz, fazovye prevrashcheniya i diagrammy sostoyaniya metallicheskikh sistem. Nauka, Moskva, p 198

    Google Scholar 

  10. Lantratov MF, Tsarenko EV (1961) Zh Prikladnoi Khimii 34: 2435

    Google Scholar 

  11. Tamaki S, Cusack NE (1979) J Phys F: Metal Phys 9: 403

    Google Scholar 

  12. Zabdyr L, Fitzner K (1983) Archiw Hutn 28: 221

    Google Scholar 

  13. Pelton AD, Flengas SN (1969) Can J Chem 47: 2283

    Google Scholar 

  14. Bhatia AB, Thornton DE (1970) Phys Rev B 2: 3004

    Google Scholar 

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Dedicated to Prof. Dr.Kurt L. Komarek on the occasion of his 60th birthday.

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Zabdyr, L.A. Thermodynamics and phase diagram of the gallium-sodium system. Monatsh Chem 119, 31–40 (1988). https://doi.org/10.1007/BF00810084

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  • DOI: https://doi.org/10.1007/BF00810084

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