Skip to main content
SpringerLink
Log in

Synthesis of aluminum rich MCM-41

  • Published:
Catalysis Letters Aims and scope Submit manuscript

Abstract

The synthesis of MCM-41 mesoporous compounds with Si/Al ratios as low as 2 without observing the presence of octahedral Al in27AlMAS NMR is reported. FTIR spectra of chemisorbed pyridine indicated that MCM-41 materials in their protonated form exhibit both Brønsted and Lewis acid sites.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. C.T. Kresge, M.E. Leonowicz, W.J. Roth, J.C. Vartuli and J.S. Beck, Nature 359 (1992) 710.

    Google Scholar 

  2. J.S. Beck, J.C. Vartuli, W.J. Roth, M.E. Leonowicz, C.T. Kresge, K.D. Schmitt, C.T.W. Chu, D.H. Olson, E.W. Sheppard, S.B. McCullen, J.B. Higgins and J.L. Schlenker, J. Am. Chem. Soc. 114 (1992) 10834.

    Google Scholar 

  3. A. Monnier, F. Schuth, Q. Huo, D. Kumar, D. Margolese, R.S. Maxwell, G.D. Stucky, M. Krishnamurthy, P. Petroff, A. Firouzi, M. Janicke and B.F. Chmelka, Science 261 (1993) 1299.

    Google Scholar 

  4. J.C. Vartuli, K.D. Schmitt, C.T. Kresge, W.J. Roth, M.E. Leonowicz, S.B. McCullen, S.D. Hellring, J.S. Beck, J.L. Schlenker, D.H. Olson and E.W. Sheppard, Stud. Surf. Sci. Catal. 84 (1994) 53.

    Google Scholar 

  5. Q. Huo, D.I. Margolese, U. Ciesla, D.G. Demuth, P. Feng, T.E. Gier, P. Sieger, A. Firouzi, B.F. Chemelka, F. Schuth and G.D. Stucky, Chem. Mater. 6 (1994) 1176.

    Google Scholar 

  6. R. Schmidt, D. Akporiaye, M. Stocker and O.H. Ellestad, Stud. Surf. Sci. Catal. 85 (1994) 61.

    Google Scholar 

  7. M. Janicke, D. Kumar, G.D. Stucky and B.F. Chmelka, Stud. Surf. Sci. Catal. 84 (1994) 243.

    Google Scholar 

  8. C.-Y. Chen, H.-X. Li and M. Davis, Microporous Mater. 2 (1993) 17.

    Google Scholar 

  9. C.-Y. Chen, S.L. Burkett, H.-X. Li and M. Davis, Microporous Mater. 2 (1993) 27.

    Google Scholar 

  10. R.B. Borade and A. Clearfield, J. Phys. Chem. 96 (1992) 6729.

    Google Scholar 

  11. A. Corma, V. Fornes, M.T. Navarro and J.P. Pariente, J. Catal. 148 (1994) 569.

    Google Scholar 

  12. P.T. Tanev, M. Chibwe and T.J. Pinnavaia, Nature 368 (1994) 321.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Chemistry, Texas A&M University, 77843, College Station, TX, USA

    Ramesh B. Borade & Abraham Clearfield

Authors
  1. Ramesh B. Borade
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Abraham Clearfield
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Borade, R.B., Clearfield, A. Synthesis of aluminum rich MCM-41. Catal Lett 31, 267–272 (1995). https://doi.org/10.1007/BF00808839

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00808839

Keywords

Search

Navigation