Abstract
Rapid synthesis of branched alkanes in the gasoline range from propene was conducted using a series reactor. Alkenes in the gasoline range produced on the MFI type H-Fe-silicate packed in the first-stage reactor were successively hydrogenated on various Pt-modified catalysts packed in the second-stage reactor. Even at high space velocity, the selectivity to branched alkanes including cycloalkanes in the gasoline range was greatly increased by adopting the Pt-modified mesoporous silicate, compared with that of Pt-modified MFI type non-metal silicate and/or silica gel having a distribution of pores in the mesoporous range. The mesoporous silicate was synthesized from kanemite by repeated ion-exchange treatment with an aqueous solution of hexadecyltrimethylammonium chloride.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
J.S. Beck, J.C. Vartuli, W.J. Roth, M.E. Leonowicz, C.T. Kresge, K.D. Schmitt, C.T.-W. Chu, D.H. Olson, E.W. Sheppard, S.B. McCullen, J.B. Higgins and J.L. Schlenker, J. Am. Chem. Soc. 114 (1992) 10834.
C.T. Kresge, M.E. Leonowicz, W.J. Roth, J.C. Vartuli and J.S. Beck, Nature 359 (1992) 710.
S. Inagaki, Y. Fukushima, A. Okada, T. Kurauchi, K. Kuroda and C. Kato, in:Proc. 9th Int. Zeolite Conf., eds. R. von Ballmoos, J.B. Higgins and M.M.J. Treacy (Butterworth-Heinemann, Boston, 1992) p. 305.
S. Inagaki, Y. Fukushima and K. Kuroda, J. Chem. Soc. Chem. Commun. (1993) 680.
T. Inui, J. Tarumoto, F. Okazumi and H. Matsuda, Chem. Express 1 (1986) 49.
T. Inui, React. Kinet. Catal. Lett. 35 (1987) 227.
T. Inui, F. Okazumi, J. Tarumoto, O. Yamase, H. Matsuda, H. Nagata, N. Daito and A. Miyamoto, J. Japan. Petrol. Inst. 30 (1987) 249.
J.-B. Kim, T. Takeguchi and T. Inui, in:Preprints Int. Symp. on Zeolites and Microporous Crystals, Nagoya 1993, p. 341.
T. Inui, O. Yamase, K. Fukuda, A. Itoh, J. Tarumoto, N. Morinaga, T. Hagiwara and Y. Takegami, in:Proc. 8th Int. Congr. on Catalysis, Berlin, 2 July 1984, Vol. III (Verlag-Chemie, Weinheim, 1984) p. 569.
T. Inui, in:Zeolite Synthesis, ACS Symp. Ser., Vol. 398, eds. M.L. Occelli and H.E. Robinson (Am. Chem. Soc., Washington, 1989) p. 479.
K. Beneke and G. Lagaly, Am. Mineral. 62 (1977) 763.
N.Y. Chen and W.E. Garwood, J. Catal. 52 (1978) 453.
V.Y. Frillette, W.O. Haag and R.M. Lago, J. Catal. 67 (1981) 218.
R.M. Dessau, J. Catal. 89 (1984) 520.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Inui, T., Kim, J.B. & Seno, M. Application of mesoporous crystalline silicates to a good catalyst support for gasoline synthesis. Catal Lett 29, 271–279 (1994). https://doi.org/10.1007/BF00807106
Received:
Accepted:
Issue Date:
DOI: https://doi.org/10.1007/BF00807106