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HREELS/TDS study of NO reaction with hydrogen on Pt(100) surface

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Abstract

NO adsorption on a Pt(100)-(hex) surface and NOads reaction with hydrogen at 300 K have been studied by HREELS, LEED, TDS and isothermal desorption. NO adsorbs in molecular form, its molecules gathering in islands with a high local coverage. Surface reconstruction into a (1 × 1) phase proceeds within the boundaries of islands. Reaction NO + H2 is performed via NOads previous heating in vacuum atT h = 375–425 K. Kinetics of NOads titration appears to be autocatalytic. Nitrogen is the major reaction product.

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References

  1. R.I. Masel, Catal. Rev.-Sci. Eng. 28 (1986) 335.

    Google Scholar 

  2. H.P. Bonzel, G. Broden and G. Pirug, J. Catal. 53 (1978) 96.

    Google Scholar 

  3. G. Pirug, H.P. Bonzel, H. Hopster and H. Ibach, J. Chem. Phys. 71 (1979) 593.

    Google Scholar 

  4. S.B. Schwartz and L.D. Schmidt, Surf. Sci. 206 (1988) 169.

    Google Scholar 

  5. T. Fink, J.-P. Dath, R. Imbihl and G. Ertl, J. Chem. Phys. 95 (1991) 2109.

    Google Scholar 

  6. M. Slinko, T. Fink, T. Loher, H.H. Madden, S.J. Lombardo, R. Imbihl and G. Ertl,Proc. 10th Int. Congr. on Catalysis, Part B, Budapest 1992, eds. L. Guczi, T. Solymosi and P. Tétényi (Akadémiai Kiadó, Budapest, 1993).

    Google Scholar 

  7. M.W. Lesley and L.D. Schmidt, Surf. Sci. 155 (1985) 215.

    Google Scholar 

  8. T. Fink, J.-P. Dath, M.R. Bassett, R. Imbihl and G. Ertl, Surf. Sci. 245 (1990) 96.

    Google Scholar 

  9. H.H. Madden and R. Imbihl, Appl. Surf. Sci. 48/49 (1991) 130.

    Google Scholar 

  10. P. Gardner, M. Tushaus, R. Martin and A.M. Bradshaw, Surf. Sci. 240 (1990) 112.

    Google Scholar 

  11. V.A. Sobyanin, React. Kinet. Catal. Lett. 32 (1986) 287.

    Google Scholar 

  12. R.J. Gorte, L.D. Schmidt and J.L. Gland, Surf. Sci. 109 (1981) 367.

    Google Scholar 

  13. G. Broden, G. Pirug and H.P. Bonzel, Surf. Sci. 72 (1978) 45.

    Google Scholar 

  14. M.A. Barteau, E.I. Ko and R.J. Madix, Surf. Sci. 102 (1981) 99.

    Google Scholar 

  15. E. Ritter, R.J. Behm, G. Potschke and J. Wintterlin, Surf. Sci. 181 (1987) 403.

    Google Scholar 

  16. W.F. Banholzer and R.I. Masel, Surf. Sci. 137 (1984) 339.

    Google Scholar 

  17. D.Yu. Zemlyanov, M.Yu. Smirnov and V.V. Gorodetskii, Physics of Low Dimension Structure, accepted.

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Authors and Affiliations

  1. Boreskov Institute of Catalysis, 630090, Novosibirsk, Russia

    D. Yu. Zemlyanov, M. Yu. Smirnov & V. V. Gorodetskii

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  1. D. Yu. Zemlyanov
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  2. M. Yu. Smirnov
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  3. V. V. Gorodetskii
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Zemlyanov, D.Y., Smirnov, M.Y. & Gorodetskii, V.V. HREELS/TDS study of NO reaction with hydrogen on Pt(100) surface. Catal Lett 28, 153–160 (1994). https://doi.org/10.1007/BF00806044

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  • DOI: https://doi.org/10.1007/BF00806044

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