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New type of organocobalt complexes structure of η2-aminomethylenebis(2,2′-bipyridyl) cobalt (III)

Ein neuer Typ von Organo-Kobaltkomplexen. Struktur von η2-Aminomethylenbis(2,2′-bipyridyl)-kobalt (III) (Kurze Mitteilung)

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  • Anorganische Und Physikalische Chemie
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Abstract

The cations Cobipy 2(CH2NH2)2+ formed through the photodecarboxylation of Cobipy 2(O2CCH2NH2)2+ have been shown by single-crystal X-ray diffraction to contain the three-membered Co-C-N cycles, with Co-C, Co-N, and C-N distances being 195, 194, and 141 pm respectively.

Zusammenfassung

Die durch Photodecarboxylierung von Cobipy 2(O2CCH2NH2)2+ gewonnenen Kationen Cobipy 2(CH2NH2)2+ enthalten einen dreigliederigen Ring Co-C-N der durch Einkristall-Röntgenstrukturanalyse bestätigt wurde. Die gefundenen Co-C-, Co-N- und C-N-Abstände betragen 195, 194 und 141 pm.

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Authors and Affiliations

  1. Institute of Physics, BSSR Academy of Sciences, Minsk, USSR

    A. L. Poznyak & V. I. Pavlovski

  2. Department of Chemistry, Lomonosov State University, Moscow, USSR

    E. B. Chuklanova, T. N. Polynova & M. A. Porai-Koshits

Authors
  1. A. L. Poznyak
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  2. V. I. Pavlovski
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  3. E. B. Chuklanova
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  4. T. N. Polynova
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  5. M. A. Porai-Koshits
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Poznyak, A.L., Pavlovski, V.I., Chuklanova, E.B. et al. New type of organocobalt complexes structure of η2-aminomethylenebis(2,2′-bipyridyl) cobalt (III). Monatsh Chem 113, 561–564 (1982). https://doi.org/10.1007/BF00800262

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  • DOI: https://doi.org/10.1007/BF00800262

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