Abstract
The structural changes occurring in the template-free SAPO-5 and SAPO-34 upon the rehydration are reversible and do not affect their acidity and catalytic activity. The rehydrated SAPO-37 loses irreversibly a considerable part of its initial crystallinity, surface area, acidity and catalytic activity. Nevertheless the remaining acid centers are stable against dehydrationrehydration cycles.
Similar content being viewed by others
References
M. Goepper, F. Guth, L. Delamotte, J.L. Guth and R. Kessletr, Stud. Surf. Sci. Catal. 49 (1989) 857.
B. Zibrowius, E. Loeffler and I. Girnus, in:3rd German Workshop on Zeolite Chemistry (Fritz Hober Inst. Max Planck Gesell., Berlin, 1991) p. 6.
M. Briend, A. Shikloleslami, M.J. Peltre, D. Delafosse and D. Barthomeuf, J. Chem. Soc. Dalton Trans. (1989) 1361.
A. Corma, V. Fornes, M.J. Franco, F.A. Mocholi and J. Perez-Pariente, ACS Symp. Series 452 (1991) 79.
N. Dumont, T. Ito and E. Derouane, Appl. Catal. 54 (1989) L1-L6.
P.A. Jacobs,Carboniogenic Activity of Zeolites (Elsevier, Amsterdam, 1977).
EP 103117.
H. Weyda and H. Lechert, Stud. Surf. Sci. Catal. 49 (1989) 169.
V. Kanazirev and N.N. Borisova, Zeolites 2 (1982) 23.
V. Kanazirev and T. Tsoncheva, Zeolites 9 (1989) 516.
R.A. Van Nordstrand, D.S. Santilli and S.I. Zones, ACS Symp. Series 368 (1988) 236.
L.S. Saldarriaga, C. Saldarriaga and M.E. Davis, J. Am. Chem. Soc. 109 (1987) 2686.
K.J. Chao and L.J. Leu, Stud. Surf. Sci. Catal. 46 (1989) 19.
Ch. Minchev, V. Kanazirev, V. Mavrodinova, V. Penchev and H. Lechert, Stud. Surf. Sci. Catal. 46 (1989) 29.
J. Jaenchen, V. Penchev, E. Loeffler, B. Parlitz and H. Stach, Collect. Czech. Chem. Commun. 57 (1992) 826.
B. Zibrowius, E. Loeffler and M. Hunger, Zeolites 12 (1992) 167.
M. Briend, A. Lamy, S. Dzwigaj and D. Barthomeuf, Stud. Surf. Sci. Catal. 9 (1991) 313.
V. Penchev, V. Kanazirev and Ch. Minchev, Neftekhimija 19 (1979) 672.
H.G. Karge, K. Hatada, Y. Zhang and R. Fiedorow, Zeolites 3 (1983) 13.
M. Peltre, M. Briend, A. Lamy and D. Barthomeuf, J. Chem. Soc. Faraday Trans. 86 (1990) 3823.
J. Martens, P. Grobet and P. Jacobs, J. Catal. 12 (1990) 299.
M. Briend, M. Derewinski, A. Lamy and D. Barthomeuf, in:Preprint and Abstract Book, 10th Int. Congr. on Catalysis (Inst. of Isotopes, Hungarian Academy of Sci., Budapest, 1992) p. 49.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Minchev, Neinska, Y., Valtchev, V. et al. Effect of the rehydration on the acidity and catalytic activity of SAPO molecular sieves. Catal Lett 18, 125–135 (1993). https://doi.org/10.1007/BF00769505
Received:
Accepted:
Issue Date:
DOI: https://doi.org/10.1007/BF00769505