Skip to main content
Log in

Effect of the rehydration on the acidity and catalytic activity of SAPO molecular sieves

  • Published:
Catalysis Letters Aims and scope Submit manuscript

Abstract

The structural changes occurring in the template-free SAPO-5 and SAPO-34 upon the rehydration are reversible and do not affect their acidity and catalytic activity. The rehydrated SAPO-37 loses irreversibly a considerable part of its initial crystallinity, surface area, acidity and catalytic activity. Nevertheless the remaining acid centers are stable against dehydrationrehydration cycles.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. M. Goepper, F. Guth, L. Delamotte, J.L. Guth and R. Kessletr, Stud. Surf. Sci. Catal. 49 (1989) 857.

    Google Scholar 

  2. B. Zibrowius, E. Loeffler and I. Girnus, in:3rd German Workshop on Zeolite Chemistry (Fritz Hober Inst. Max Planck Gesell., Berlin, 1991) p. 6.

    Google Scholar 

  3. M. Briend, A. Shikloleslami, M.J. Peltre, D. Delafosse and D. Barthomeuf, J. Chem. Soc. Dalton Trans. (1989) 1361.

  4. A. Corma, V. Fornes, M.J. Franco, F.A. Mocholi and J. Perez-Pariente, ACS Symp. Series 452 (1991) 79.

    Google Scholar 

  5. N. Dumont, T. Ito and E. Derouane, Appl. Catal. 54 (1989) L1-L6.

    Google Scholar 

  6. P.A. Jacobs,Carboniogenic Activity of Zeolites (Elsevier, Amsterdam, 1977).

    Google Scholar 

  7. EP 103117.

  8. H. Weyda and H. Lechert, Stud. Surf. Sci. Catal. 49 (1989) 169.

    Google Scholar 

  9. V. Kanazirev and N.N. Borisova, Zeolites 2 (1982) 23.

    Google Scholar 

  10. V. Kanazirev and T. Tsoncheva, Zeolites 9 (1989) 516.

    Google Scholar 

  11. R.A. Van Nordstrand, D.S. Santilli and S.I. Zones, ACS Symp. Series 368 (1988) 236.

    Google Scholar 

  12. L.S. Saldarriaga, C. Saldarriaga and M.E. Davis, J. Am. Chem. Soc. 109 (1987) 2686.

    Google Scholar 

  13. K.J. Chao and L.J. Leu, Stud. Surf. Sci. Catal. 46 (1989) 19.

    Google Scholar 

  14. Ch. Minchev, V. Kanazirev, V. Mavrodinova, V. Penchev and H. Lechert, Stud. Surf. Sci. Catal. 46 (1989) 29.

    Google Scholar 

  15. J. Jaenchen, V. Penchev, E. Loeffler, B. Parlitz and H. Stach, Collect. Czech. Chem. Commun. 57 (1992) 826.

    Google Scholar 

  16. B. Zibrowius, E. Loeffler and M. Hunger, Zeolites 12 (1992) 167.

    Google Scholar 

  17. M. Briend, A. Lamy, S. Dzwigaj and D. Barthomeuf, Stud. Surf. Sci. Catal. 9 (1991) 313.

    Google Scholar 

  18. V. Penchev, V. Kanazirev and Ch. Minchev, Neftekhimija 19 (1979) 672.

    Google Scholar 

  19. H.G. Karge, K. Hatada, Y. Zhang and R. Fiedorow, Zeolites 3 (1983) 13.

    Google Scholar 

  20. M. Peltre, M. Briend, A. Lamy and D. Barthomeuf, J. Chem. Soc. Faraday Trans. 86 (1990) 3823.

    Google Scholar 

  21. J. Martens, P. Grobet and P. Jacobs, J. Catal. 12 (1990) 299.

    Google Scholar 

  22. M. Briend, M. Derewinski, A. Lamy and D. Barthomeuf, in:Preprint and Abstract Book, 10th Int. Congr. on Catalysis (Inst. of Isotopes, Hungarian Academy of Sci., Budapest, 1992) p. 49.

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Minchev, Neinska, Y., Valtchev, V. et al. Effect of the rehydration on the acidity and catalytic activity of SAPO molecular sieves. Catal Lett 18, 125–135 (1993). https://doi.org/10.1007/BF00769505

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00769505

Keywords

Navigation