Abstract
Solid-state nuclear magnetic resonance techniques have been used to show that CO adsorbs in a molecular state on γ-Mo2N (fcc). An axially symmetric chemical shift powder pattern is observed for13CO adsorbed at 298 K. The observed lineshape is very similar to that observed for Mo(CO)6. Lineshapes for the α (hcp) and β (fcc) phases of Mo2C were also recorded for comparison.
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Haddix, G.W., Bell, A.T. & Reimer, J.A. Characterization of CO adsorbed on γ-Mo2N by NMR spectroscopy. Catal Lett 1, 207–212 (1988). https://doi.org/10.1007/BF00766176
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DOI: https://doi.org/10.1007/BF00766176